Struktur-Reaktivität-Gleichungen und ihre Anwendung zur Bestimmung organischer Reaktionsmechanismen
CHIMIA, 1973 Several examples of the application of structure-reactivity correlations to the determination of organic reaction mechanisms are discussed. As a first example, our results on the photochlorination of aliphatic compounds are considered.
A. Bruylants
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Identity and function of an essential nitrogen ligand of the nitrogenase cofactor biosynthesis protein NifB. [PDF]
, 2020 NifB is a radical S-adenosyl-L-methionine (SAM) enzyme that is essential for nitrogenase cofactor assembly. Previously, a nitrogen ligand was shown to be involved in coupling a pair of [Fe4S4] clusters (designated K1 and K2) concomitant with carbide ...
Britt, R David +7 more
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Which Chromium–Sulfur Compounds Exist as 2D Material?
Advanced Functional Materials, EarlyView.2D chromium sulfides synthesized using molecular beam epitaxy on graphene. Structural characterization reveals two novel 2D materials, Cr2S3‐2D, which lacks a direct bulk counterpart, and Cr223S${\rm Cr}_{2\frac{2}{3}}{\rm S}$4‐2D, a minimum thickness version of Cr5S6. However, attempts to synthesize CrS2 are unsuccessful. Both new 2D phases are stable
Affan Safeer +5 more
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Journal of Physical Chemistry A, 2013 This work details an ab initio and chemical kinetic study of the hydrogen atom abstraction reactions by the hydroperoxyl radical (HȮ2) on the following esters: methyl ethanoate, methyl propanoate, methyl butanoate, methyl pentanoate, methyl isobutyrate ...
Jorge Mendes, Chong-Wen Zhou, H. Curran
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Advanced Functional Materials, EarlyView.Heterojunctions combining halide perovskites with low‐dimensional materials enhance optoelectronic devices by enabling precise charge control and improving efficiency, stability, and speed. These synergies advance flexible electronics, wearable sensors, and neuromorphic computing, mimicking biological vision for real‐time image analysis and intelligent
Yu‐Jin Du +11 more
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Structure-dependent reactivity of oxyfunctionalized acetophenones in the photooxidation of DNA: base oxidation and strand breaks through photolytic radical formation (spin trapping, EPR spectroscopy, transient kinetics) versus photosensitization (electron transfer, hydrogen-atom abstraction) [PDF]
, 2001 Waldemar Adam
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, 2013 We recently showed that dispersion-correcting potentials (DCPs), atom-centered Gaussian-type functions developed for use with B3LYP (J. Phys. Chem. Lett.
DiLabio, Gino A. +2 more
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Engineering Strategies for 2D Layered Tin Halide Perovskite Field‐Effect Transistors
Advanced Functional Materials, EarlyView.2D halide perovskites are promising candidates for field‐effect transistor (FET) applications due to their high stability and suppressed ion migration in the presence of bulky organic spacers. This review systematically summarizes the optimization engineering strategies of 2D perovskite FETs and future challenges, which provide guidance for developing ...
Shuanglong Wang +4 more
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Hydrogen Atom Abstraction by a Cumyloxy Radical [PDF]
Bulletin of the Chemical Society of Japan, 1968 Nobuto Ohta, Etsuo Niki, Yoshio Kamiya
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Iridium Oxide Inverse Opal Anodes with Tailored Porosity for Efficient PEM Electrolysis
Advanced Functional Materials, EarlyView.The synthesis of Iridium‐based Inverse Opals (Ir‐IO) is reported as electrocatalyst for Proton exchange membrane water electrolysis (PEM‐WE). Using the developed protocol it produces highly porous materials consisting either of metallic, oxidic Iridium or a combination thereof with large surface areas.
Sebastian Möhle +2 more
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