Results 11 to 20 of about 188,936 (339)

Hydrogen Atom Abstraction and Reduction Study of 21-Thiaporphyrin and 21,23-Dithiaporphyrin. [PDF]

Molecules
The metal-free porphyrins protonation has gained interest over five decades because its structure modification and hardly monoacid intermediate isolation.
Ren XR, Xing K, Liu T, Cao R, Dang LL, Bai F, Duan PC.   +6 more
europepmc   +5 more sources

Tunnelling dominates the reactions of hydrogen atoms with unsaturated alcohols and aldehydes in the dense medium [PDF]

, 2018
Hydrogen addition and abstraction reactions play an important role as surface reactions in the buildup of complex organic molecules in the dense interstellar medium. Addition reactions allow unsaturated bonds to be fully hydrogenated, while abstraction reactions recreate radicals that may undergo radical-radical recombination reactions.
Kästner, J., Lamberts, T., Markmeyer, M. N., Zaverkin, V.   +3 more
arxiv   +3 more sources

Mechanistic insights into the oxidation of substituted phenols via hydrogen atom abstraction by a cupric-superoxo complex. [PDF]

J Am Chem Soc, 2014
Lee JY, Peterson RL, Ohkubo K, Garcia-Bosch I, Himes RA, Woertink J, Moore CD, Solomon EI, Fukuzumi S, Karlin KD.   +9 more
europepmc   +2 more sources

KINETICS OF THE ABSTRACTION OF HYDROGEN ATOMS FROM HYDROGEN SULFIDE BY TRIFLUOROMETHYL RADICALS [PDF]

Canadian Journal of Chemistry, 1966
Trifluoromethyl radicals generated from the photolysis of hexafluoroacetone abstract hydrogen atoms from hydrogen sulphide.[Formula: see text]The rate constant of this reaction measured by comparing the rate with that for the recombination of trifluoromethyl radicals (k = 2.3 × 1013 cc mole−1 s−1) is given by,[Formula: see text]
Neville L. Arthur, T. N. Bell
openalex   +3 more sources

DNA double strand cleavage via interstrand hydrogen atom abstraction. [PDF]

J Am Chem Soc, 2013
Taverna Porro ML, Greenberg MM.
europepmc   +3 more sources

Hydrogen atom abstraction as a synthetic route to a square planar Co^II complex with a redox-active tetradentate PNNP ligand. [PDF]

Chem Sci
Miller JD, Walsh MM, Lee K, Moore CE, Thomas CM.   +4 more
europepmc   +2 more sources

Hydrogen atom abstraction by peroxy radicals [PDF]

Canadian Journal of Chemistry, 1967
B. Middleton, K. U. Ingold
openalex   +3 more sources

A comparison of hydrogen abstraction reaction between allyl-type monomers with thioxanthone-based photoinitiators without amine synergists

Frontiers in Chemistry, 2022
The photodriven radical-mediated [3 + 2] cyclization reaction was found to yield polymers efficiently without being hindered by degradative chain transfer.
Xiaotian Zhao, Wen Xu, Xi Chen, Shibo Lin, Xuanhao Li, Lihui He, Xu Liao, Guodong Ye   +7 more
doaj   +1 more source

Photoinduced Ring Opening of Methyl 1-Aryl-5-oxo-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazole-2-carboxylates in the Presence of Diaryl Disulfides

Molbank, 2023
Among the methods used for the synthesis of functionalized heterocyclic compounds, photochemistry has gained immense popularity due to the reactivity of intermediates in photoinduced reactions.
Nejc Petek, Uroš Grošelj
doaj   +1 more source

Ab initio chemical kinetics of Isopropyl acetate oxidation with OH radicals

Green Chemistry Letters and Reviews, 2023
Global reactivity descriptors of isopropyl acetate (IPA) and thermo-kinetic aspects of its oxidation via OH radicals have been studied. Transition state theory (TST) was utilized to estimate the bimolecular rate constants.
Mohamed A. Abdel-Rahman, Mohamed F. Shibl, Abolfazl Shiroudi, Mohamed A. M. Mahmoud   +3 more
doaj   +1 more source