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KINETICS OF THE ABSTRACTION OF HYDROGEN ATOMS FROM HYDROGEN SULFIDE BY TRIFLUOROMETHYL RADICALS [PDF]

open access: bronzeCanadian Journal of Chemistry, 1966
Trifluoromethyl radicals generated from the photolysis of hexafluoroacetone abstract hydrogen atoms from hydrogen sulphide.[Formula: see text]The rate constant of this reaction measured by comparing the rate with that for the recombination of trifluoromethyl radicals (k = 2.3 × 1013 cc mole−1 s−1) is given by,[Formula: see text]
T. N. Bell, N. L. Arthur
openaire   +3 more sources

Oxidation of norbornadiene: Theoretical investigation on H-atom abstraction and related radical decomposition reactions

open access: yesPropulsion and Power Research, 2023
The chemical kinetics of hydrogen atom (H-atom) abstraction reactions from norbornadiene (NBD) by five radicals (H, O(3P), OH, CH3, and HO2), and the unimolecular reactions of three NBD derived radicals, were studied through high-level ab-initio ...
Jintao Chen   +6 more
doaj   +1 more source

A comparison of hydrogen abstraction reaction between allyl-type monomers with thioxanthone-based photoinitiators without amine synergists

open access: yesFrontiers in Chemistry, 2022
The photodriven radical-mediated [3 + 2] cyclization reaction was found to yield polymers efficiently without being hindered by degradative chain transfer.
Xiaotian Zhao   +7 more
doaj   +1 more source

Photoinduced Ring Opening of Methyl 1-Aryl-5-oxo-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazole-2-carboxylates in the Presence of Diaryl Disulfides

open access: yesMolbank, 2023
Among the methods used for the synthesis of functionalized heterocyclic compounds, photochemistry has gained immense popularity due to the reactivity of intermediates in photoinduced reactions.
Nejc Petek, Uroš Grošelj
doaj   +1 more source

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