Results 41 to 50 of about 205,731 (373)

Probing the Electrostatic and Steric Requirements for Substrate Binding in Human Platelet-Type 12-Lipoxygenase. [PDF]

, 2019
Human platelet ALOX12 (hALOX12 or h12-LOX) has been implicated in a variety of human diseases. The present study investigates the active site of hALOX12 to more thoroughly understand how it positions the substrate and achieves nearly perfect regio- and ...
Aleem, Ansari Mukhtar, Alvarez, Gabriella, Deschamps, Joshua, Holman, Theodore, Jacobson, Matthew P, Kalyanaraman, Chakrapani, Tena, Jennyfer, Tsai, Wan-Chen   +7 more
core   +2 more sources

Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and air

Beilstein Journal of Organic Chemistry, 2007
Experiments conducted with deuterated compounds demonstrated that during the reduction of S-alkylxanthates with triethylborane, the hydrogen atom transferred has several competing origins.
Florent Allais, Jean Boivin, Van Tai Nguyen   +2 more
doaj   +1 more source

Experimental and modeling study of the autoignition of 1-hexene/iso-octane mixtures at low temperatures [PDF]

, 2005
Autoignition delay times have been measured in a rapid compression machine at Lille at temperatures after compression from 630 to 840 K, pressures from 8 to 14 bar, \Phi = 1 and for a iso octane/1 hexene mixture containing 82% iso-octane and 18% 1 hexene.
Barbé, Battin-Leclerc, Benson, Buda, Callahan, Ciajolo, Clarkson, Curran, Curran, F. Battin-Leclerc, Fieweger, G. Vanhove, Glaude, Glaude, Gray, Heyberger, Heyberger, Klotz, Lee, Minetti, Minetti, Minetti, Minetti, Muller, P.A. Glaude, R. Fournet, R. Minetti, S. Touchard, Stark, Touchard, Vanhove, Warth, Westbrook, Yahyaoui   +33 more
core   +3 more sources

An Ab Initio RRKM-Based Master Equation Study for Kinetics of OH-Initiated Oxidation of 2-Methyltetrahydrofuran and Its Implications in Kinetic Modeling

Energies, 2023
Cyclic ethers (CEs) can be promising future biofuel candidates. Most CEs possess physico-chemical and combustion indicators comparable to conventional fuels, making them suitable for internal combustion engines. This work computationally investigates the
Tam V.-T. Mai, Thanh Q. Bui, Nguyen Thi Ai Nhung, Phan Tu Quy, Krishna Prasad Shrestha, Fabian Mauss, Binod Raj Giri, Lam K. Huynh   +7 more
doaj   +1 more source

Grain Surface Models and Data for Astrochemistry [PDF]

, 2017
The cross-disciplinary field of astrochemistry exists to understand the formation, destruction, and survival of molecules in astrophysical environments. Molecules in space are synthesized via a large variety of gas-phase reactions, and reactions on dust ...
A. Al-Halabi, A. Al-Halabi, A. Al-Halabi, A. Bacmann, A. Belloche, A. Belloche, A. Dalgarno, A. Dutrey, A. Leger, A. Lipshtat, A. McKellar, A. Nagaoka, A. Nagaoka, A. Pedersen, A. Rimola, A. Stutz, A. Tielens, A. Wolff, A.A. Boogert, A.E. Douglas, A.G.G.M. Tielens, A.G.G.M. Tielens, A.G.G.M. Tielens, A.I. Vasyunin, A.I. Vasyunin, A.S. Bolina, A.S. Bolina, A.S. Bolina, A.S. Eddington, A.V. Ivlev, B. Lepetit, B.T. Draine, B.T. Draine, C. Arasa, C. Arasa, C. Arasa, C. Chyba, C. Eckart, C. Vastel, C. Walsh, C. Walsh, C.M. Leung, D. Field, D. Hollenbach, D. McElroy, D. Semenov, D. Semenov, D.A. Adriaens, D.E. Woon, D.H. Parker, D.J. Hollenbach, D.P. Ruffle, D.P. Ruffle, D.R. Bates, D.T. Gillespie, E. Anders, E. Congiu, E. Gonzalez-Lavado, E. Herbst, E. Herbst, E. Herbst, E. Herbst, E. Herbst, E. M. Penteado, E. Wigner, E.A. Bergin, E.C. Fayolle, E.C. Fayolle, E.C. Fayolle, E.F. Dishoeck van, E.F. Dishoeck van, E.K. Campbell, E.M. Penteado, E.R. Batista, F. Dulieu, F. Mispelaer, F.L. Schöier, G. Cooper, G. Fedoseev, G. Nyman, G.A. Cruz-Diaz, G.A. Cruz-Diaz, G.A. Cruz-Diaz, G.M. Muñoz Caro, G.W. Fuchs, G.W. Fuchs, H. Chaabouni, H. Hidaka, H. Hidaka, H. Hidaka, H. Linnartz, H. M. Cuppen, H.J. Fraser, H.J. Fraser, H.M. Cuppen, H.M. Cuppen, H.M. Cuppen, J. Bossa, J. Cami, J. Cernicharo, J. Fillion, J. Gonzalez, J. He, J. He, J. Kalvāns, J. Koning, J. Kästner, J. Zhen, J.A. Noble, J.A. Noble, J.A. Noble, J.B. Bergner, J.B. Bossa, J.E. Elsila, J.K. Jørgensen, J.M.C. Rawlings, J.R. Burke, K. Acharyya, K. Acharyya, K. Furuya, K. Furuya, K. Hiraoka, K. Hiraoka, K. Hiraoka, K. Hiraoka, K. Isokoski, K. Kuwahata, K. Kvenvolden, K. Willacy, K. Willacy, K.I. Öberg, K.I. Öberg, K.I. Öberg, K.I. Öberg, K.I. Öberg, K.I. Öberg, K.I. Öberg, K.I. Öberg, K.J. Chuang, K.M. Pontoppidan, K.M. Pontoppidan, L. Allamandola, L. Amiaud, L.B. D’Hendecourt, L.B. D’Hendecourt, L.B. D’Hendecourt, L.E. Snyder, L.J. Karssemeijer, L.J. Karssemeijer, L.J. Karssemeijer, L.J. Karssemeijer, L.T. Greenberg, M. Accolla, M. Agúndez, M. Allen, M. Bertin, M. Bertin, M. Bertin, M. Minissale, M. Minissale, M. Monge-Palacios, M. Monge-Palacios, M.B. Bell, M.C. Hemert van, M.P. Collings, M.P. Collings, M.P. Collings, M.S. Westley, M.S. Westley, N. Balucani, N. Katz, N. Lippok, N. Miyauchi, N. Nishi, N. Watanabe, N. Watanabe, N. Watanabe, N. Watanabe, N.F.W. Ligterink, N.G. Adams, N.J. Mason, N.J.B. Green, O. Berné, O. Biham, P. Caselli, P. Ehrenfreund, P. Swings, P. Theule, P.A. Gerakines, P.D. Brown, P.M. Woods, Q. Chang, Q. Chang, Q. Chang, Q. Chang, R. Garrod, R. Launhardt, R. T. Garrod, R.E. Weston, R.J. Gould, R.J.A. Grim, R.M. Logan, R.P. Bell, R.T. Garrod, R.T. Garrod, R.T. Garrod, R.T. Garrod, R.T. Garrod, R.T. Garrod, R.T. Garrod, S. Andersson, S. Andersson, S. Andersson, S. Andersson, S. Cazaux, S. Ioppolo, S. Ioppolo, S. Viti, S.A. Sandford, S.A. Sandford, S.A. Sandford, S.A. Sandford, S.B. Charnley, S.B. Charnley, S.D. Green, S.E. Bisschop, S.E. Bisschop, S.S. Prasad, T. Albertsson, T. Butscher, T. Grassi, T. Hama, T. Hama, T. Hama, T. Henning, T. Lamberts, T. Lamberts, T. Lamberts, T. Lamberts, T. Lamberts, T. Lamberts, T. Lauck, T. Stantcheva, T. Stantcheva, T.I. Hasegawa, T.I. Hasegawa, T.I. Hasegawa, T.J. Millar, T.J.H. Hele, T.L. Nguyen, T.L. Nguyen, T.L. Nguyen, T.L. Nguyen, T.P.M. Goumans, T.P.M. Goumans, T.P.M. Goumans, T.P.M. Goumans, T.W. Hartquist, V. Barone, V. Buch, V. Pirronello, V. Pirronello, V. Pirronello, V. Taquet, V. Taquet, V. Wakelam, V. Wakelam, V.K. Veeraghattam, W. Hagen, W.A. Brown, W.D. Geppert, W.D. Watson, W.D. Watson, W.D. Watson, Y. Aikawa, Y. Chen, Y. Li, Y. Oba, Y. Oba, Y. Oba, Y. Oba, Y. Oba, Y. Zhang, Y.V. Suleimanov, Z. Awad   +284 more
core   +6 more sources

Acceptorless cross-dehydrogenative coupling for C(sp3)-H heteroarylation mediated by a heterogeneous GaN/ketone photocatalyst/photosensitizer system

Communications Chemistry, 2023
Alkanes are naturally abundant chemical building blocks that contain plentiful C(sp 3)-H bonds. While inert, the activation of C(sp 3)-H via hydrogen atom abstraction (HAT) stages an appealing approach to generate alkyl radicals.
Hyotaik Kang, Lida Tan, Jing-Tan Han, Chia-Yu Huang, Hui Su, Aleksei Kavun, Chao-Jun Li   +6 more
doaj   +1 more source

Selective deuteration as a tool for resolving autoxidation mechanisms in α-pinene ozonolysis [PDF]

Atmospheric Chemistry and Physics, 2023
Highly oxygenated organic molecules (HOMs) from α-pinene ozonolysis have been shown to be significant contributors to secondary organic aerosol (SOA), yet our mechanistic understanding of how the peroxy-radical-driven autoxidation leads to their ...
M. Meder, O. Peräkylä, J. G. Varelas, J. Luo, R. Cai, Y. Zhang, Y. Zhang, T. Kurtén, T. Kurtén, M. Riva, M. Rissanen, M. Rissanen, F. M. Geiger, R. J. Thomson, M. Ehn   +14 more
doaj   +1 more source

Gas phase homolytic bond dissociation enthalpies of common laboratory solvents: A G4 theoretical study [PDF]

, 2010
Gas phase standard state (298.15 K, 1 atm) calculations were conducted at the Gaussian-4 (G4) composite method level of theory to estimate the bond dissociation enthalpies (BDEs) of various common laboratory solvents.
Kaya Forest, Sierra Rayne
core   +2 more sources

Chemical dynamics of triacetylene formation and implications to the synthesis of polyynes in Titan's atmosphere [PDF]

, 2009
For the last four decades, the role of polyynes such as diacetylene (HCCCCH) and triacetylene (HCCCCCCH) in the chemical evolution of the atmosphere of Saturn's moon Titan has been a subject of vigorous research. These polyacetylenes are thought to serve
A. M. Mebel, Gladstone, Gu, Guo, Jones, Kislov, Landera, Lorenz, M. C. Liang, Porco, R. I. Kaiser, Waite, X. Gu, Y. L. Yung, Y. S. Kim   +14 more
core   +2 more sources

Remote functionalization by tandem radical chain reactions [PDF]

, 1997
Normal radical relay chlorination of cholestan-3α-ol directed by an attached m-iodobenzoate ester group affords a 9α-chloro steroid, but when the same reaction is conducted in the presence of an excess of CBr4 the product is a 9α-bromo steroid ...
Wiedenfeld, David
core   +1 more source