Results 51 to 60 of about 1,088 (243)

In‐Situ Growth of 2D MOFs as a Molecular Sieving Layer on SnS2 Nanoflakes for Realizing Ultraselective H2S Detection

Advanced Functional Materials, Volume 35, Issue 12, March 18, 2025.
The ultraselective H2S detection of the ZIF‐L/SnS2 heterostructure is demonstrated. The introduction of 2‐dimensional (2D) breathable ZIF‐L results in a substantial increase in H2S selectivity attributable to the molecular sieving effect, which impedes the permeation of gases with large kinetic diameters and high polarity.
Soo Min Lee, Yeong Jae Kim, Seon Ju Park, Woo Seok Cheon, Jaehyun Kim, Gi Baek Nam, Youngeun Kim, Ho Won Jang   +7 more
wiley   +1 more source

Using Variable and Fixed Topological Indices for the Prediction of Reaction Rate Constants of Volatile Unsaturated Hydrocarbons with OH Radicals

Molecules, 2004
mVolatile organic compounds (VOCs) play an important role in differentphotochemical processes in the troposphere. In order to predict their impact on ozoneformation processes a detailed knowledge about their abundance in the atmosphere as wellas their ...
Alexandru T. Balaban, Milan Randić, Marjan Veber, Matevž Pompe   +3 more
doaj   +1 more source

Fibrous Pb(II)‐Based Coordination Polymer Operable as a Photocatalyst and Electrocatalyst for High‐Rate, Selective CO2‐to‐Formate Conversion

Advanced Functional Materials, EarlyView.
A coordination polymer [Pb(tadt)]n prepared by a microwave‐assisted solvothermal method selectively reduces CO2 into formate under visible light with a high apparent quantum yield of ≈25% at 400 nm. It can function as a pre‐catalyst, along with conductive Ketjen Black, to form an active PbCO3/Pb3(CO3)2(OH)2 mixture that exhibits a high Faradaic ...
Chomponoot Suppaso, Ryosuke Nakazato, Shoko Nakahata, Yoshinobu Kamakura, Fumitaka Ishiwari, Akinori Saeki, Daisuke Tanaka, Kazuhide Kamiya, Kazuhiko Maeda   +8 more
wiley   +1 more source

Analyzing hydroxyl radical accessibility related to hydrogen abstraction in a DNA sugar moiety using molecular dynamics simulations

AIP Advances
Exposure of water to ionizing radiation induces OH radical formation. Within cellular environments, the presence of OH radicals can stimulate the abstraction of hydrogen atoms from the sugar backbone of DNA.
Ryuta Kawanami, Susumu Fujiwara, Yoshiteru Yonetani, Tsukasa Aso   +3 more
doaj   +1 more source

How Are Substrate Binding and Catalysis Affected by Mutating Glu127 and Arg161 in Prolyl-4-hydroxylase? A QM/MM and MD Study

Frontiers in Chemistry, 2017
Prolyl-4-hydroxylase is a vital enzyme for human physiology involved in the biosynthesis of 4-hydroxyproline, an essential component for collagen formation.
Amy Timmins, Sam P. de Visser
doaj   +1 more source

In Situ Formation of a Melt‐Solid Interface Toward Stable Oxygen Reduction in Protonic Ceramic Fuel Cells

Advanced Functional Materials, Volume 35, Issue 12, March 18, 2025.
Protonic ceramic fuel cells offer a promising route to generate power efficiently but face critical challenges in achieving industrially viable activity and stability at their cathodes in CO2‐containing air. This report proposes a new cathode material design strategy to enable the cathode to be both catalytically active and CO2 tolerant through the ...
Desheng Feng, Mengran Li, Vanessa K. Peterson, Rijia Lin, Anita D'Angelo, Olexandra Marenych, Anya Yago, Dominique Appadoo, Tianjiu Zhu, Muhammad Yazid Bin Zulkifli, Shuai Gao, Yuming Wu, Xiaohe Tian, Xiaoyang Du, Zhonghua Zhu   +14 more
wiley   +1 more source

Shuttle HAT for mild alkene transfer hydrofunctionalization

Nature Communications
Hydrogen atom transfer (HAT) from a metal-hydride is a reliable and powerful method for functionalizing unsaturated C–C bonds in organic synthesis. Cobalt hydrides (Co–H) have garnered significant attention in this field, where the weak Co–H bonds are ...
Tanner C. Jankins, Philip M. Blank, Andrea Brugnetti, Philip Boehm, Françoise A. Aouane, Bill Morandi   +5 more
doaj   +1 more source

Radicals initiated by gamma rays in selected amino acids and collagen

Nukleonika, 2019
Calf skin collagen and three amino acids essential for its structure, namely glycine, L-proline and 4-hydroxyl-L-proline, were irradiated with gamma rays up to a dose of 10 kGy.
Przybytniak Grażyna, Sadło Jarosław, Dąbrowska Małgorzata, Zimek Zbigniew   +3 more
doaj   +1 more source

THE DYNAMICS OF HYDROGEN ATOM ABSTRACTION FROM POLYATOMIC MOLECULES [PDF]

, 2004
The hydrogen atom abstraction reaction is an important fundamental process that is extensively involved in atmospheric and combustion chemistry. The practical significance of this type of reaction with polyatomic hydrocarbons is manifest, which has led to many kinetics studies.
Liu, X., Suits, A. G.
openaire   +2 more sources

Deciphering the Origin of Higher Shell Coordination on Single Iron Catalysts for Resilient Modulating Persulfate Oxidation Into Singlet Oxygen Pathway

Advanced Functional Materials, Volume 35, Issue 12, March 18, 2025.
This study reveals that higher shell S coordination can effectively modulate the spin state of FeN4 site via long‐range electronic interactions, giving rise to the oriented generation of singlet oxygen from peroxymonosulfate activation. Abstract Precise manipulation of coordination structure of single‐atom sites and establishment of schematic ...
Liang Zhang, Kai Cheng, Zhizhi Yang, Ye Zhang, Shiro Kubuki, Paul A. Bingham, Yang‐Chun Yong, Bofan Zhang, Xiaoguang Duan   +8 more
wiley   +1 more source