5 S,15 S-Dihydroperoxyeicosatetraenoic Acid (5,15-diHpETE) as a Lipoxin Intermediate: Reactivity and Kinetics with Human Leukocyte 5-Lipoxygenase, Platelet 12-Lipoxygenase, and Reticulocyte 15-Lipoxygenase-1. [PDF]
The reaction of 5 S,15 S-dihydroperoxyeicosatetraenoic acid (5,15-diHpETE) with human 5-lipoxygenase (LOX), human platelet 12-LOX, and human reticulocyte 15-LOX-1 was investigated to determine the reactivity and relative rates of producing lipoxins (LXs).
Freedman, Cody+6 more
core +3 more sources
Accuracy of Calculations Involving $α^3$ Vacuum-Polarization Diagrams: Muonic Hydrogen Lamb Shift and Muon $g-2$ [PDF]
The contribution of the $\alpha^3$ single electron-loop vacuum-polarization diagrams to the Lamb shift of the muonic hydrogen has been evaluated recently by two independent methods. One uses the exact parametric representation of the vacuum-polarization function while the other relies on the Pad\'{e} approximation method. High precision of these values
arxiv +1 more source
Rate coefficient for the reaction of Cl atoms with cis-3-hexene at 296 ± 2 K [PDF]
The rate coefficient of the cis-3-hexene + Cl atoms reaction at 296 ± 2 K and 750 ± 10 Torr was determined using the relative rate technique. The reaction was investigated using an 80 L Teflon reaction bag and a gas chromatograph coupled with flame ...
Arbilla, Graciela+5 more
core +1 more source
Computational studies for reduced graphene oxide in hydrogen-rich environment [PDF]
We employ molecular dynamic simulations to study the reduction process of graphene-oxide (GO) in a chemically active environment enriched with hydrogen. We examine the concentration and pressure of hydrogen gas as a function of temperature in which abstraction of oxygen is possible with minimum damage to C-sp$^2$ bonds hence preserving the integrity of
arxiv +1 more source
A mild, operationally convenient, and practical method for the synthesis of synthetically useful N-arylsulfonylimines from N-(arylsulfonyl)benzylamines using K2S2O8 in the presence of pyridine as a base is reported herein. In addition, a “one-pot” tandem
Joydev K. Laha+2 more
doaj +1 more source
The reactive collision between Be atom and H2 molecule has received great interest both experimentally and theoretically due to its significant role in hydrogen storage, astrophysics, quantum chemistry and other fields, but the corresponding dynamics ...
Zijiang Yang, Maodu Chen
doaj +1 more source
Reactivity of the Indenyl Radical (C9 H7 ) with Acetylene (C2 H2 ) and Vinylacetylene (C4 H4 ). [PDF]
The reactions of the indenyl radicals with acetylene (C2 H2 ) and vinylacetylene (C4 H4 ) is studied in a hot chemical reactor coupled to synchrotron based vacuum ultraviolet ionization mass spectrometry.
Ablikim, Utuq+11 more
core +2 more sources
Molecular hydrogen formation on interstellar PAHs through Eley-Rideal abstraction reactions [PDF]
We present experimental data on H2 formation processes on gas-phase polycyclic aromatic hydrocarbon (PAH) cations. This process was studied by exposing coronene radical cations, confined in a radio-frequency ion trap, to gas phase H atoms. Sequential attachment of up to 23 hydrogen atoms has been observed.
arxiv +1 more source
Crosstalk between gut microbiota and tumor: tumors could cause gut dysbiosis and metabolic imbalance
In this research, we analyzed the relationship between gut microbiota and tumor. We discovered that both subcutaneous and metastatic tumors would alter the composition and metabolic function of gut microbiota. Meanwhile, fecal microbiota transplantation also indicated the anti‐tumor role of the gut microbiota, revealing the crosstalk between tumor and ...
Siyuan Zhang+8 more
wiley +1 more source
Remote functionalization by tandem radical chain reactions [PDF]
Normal radical relay chlorination of cholestan-3α-ol directed by an attached m-iodobenzoate ester group affords a 9α-chloro steroid, but when the same reaction is conducted in the presence of an excess of CBr4 the product is a 9α-bromo steroid ...
Wiedenfeld, David
core +1 more source