Results 61 to 70 of about 43,577 (345)

Bromination of hydrocarbons with CBr4, initiated by light-emitting diode irradiation

Beilstein Journal of Organic Chemistry, 2013
The bromination of hydrocarbons with CBr4 as a bromine source, induced by light-emitting diode (LED) irradiation, has been developed. Monobromides were synthesized with high efficiency without the need for any additives, catalysts, heating, or inert ...
Yuta Nishina, Bunsho Ohtani, Kotaro Kikushima   +2 more
doaj   +1 more source

Theoretical studies of a hydrogen abstraction tool for nanotechnology [PDF]

, 1991
In the design of a nanoscale, site-specific hydrogen abstraction tool, the authors suggest the use of an alkynyl radical tip. Using ab initio quantum-chemistry techniques including electron correlation they model the abstraction of hydrogen from ...
Goddard, William A., III, Merkle, Ralph C., Musgrave, Charles B., Perry, Jason K.   +3 more
core   +1 more source

Photoactivation of NV Centers in Diamond via Continuous Wave Laser Illumination of Shallow As‐Implanted Nitrogen

Advanced Functional Materials, EarlyView.
This study demonstrates an alternative method of creating charge‐stable negatively charged nitrogen vacancy (NV−) centers close to the diamond surface without high‐temperature annealing. By illuminating nitrogen‐implanted regions with a continuous‐wave 405 nm laser, NV− centers are induced, exhibiting electron spin coherence properties suitable for ...
Jens Fuhrmann, Christoph Findler, Michael Olney‐Fraser, Lev Kazak, Fedor Jelezko   +4 more
wiley   +1 more source

Cu‐Based MOF/TiO2 Composite Nanomaterials for Photocatalytic Hydrogen Generation and the Role of Copper

Advanced Functional Materials, EarlyView.
HKUST‐1/TiO2 composite materials show a very high photocatalytic hydrogen evolution rate which increases as a function of the irradiation time until reaching a plateau and even surpasses the performance of the 1%Pt/TiO2 material after three photocatalytic cycles.
Alisha Khan, Marie Le Pivert, Alireza Ranjbari, Diana Dragoe, Daniel Bahena‐Uribe, Christophe Colbeau‐Justin, Christian Herrero, Dorota Rutkowska‐Zbik, Johnny Deschamps, Hynd Remita   +9 more
wiley   +1 more source

Establishing Thermodynamic Graphs of Nitrogenous Radical Cations Abstracting Hydrogen Atoms and Their Applications in Photoredox Reactions

Molecules
Nitrogenous compounds have been extensively utilized as hydrogen atom transfer (HAT) catalysts in photoredox reactions, with nitrogenous radical cations being the actual hydrogen atom abstractors. Building upon our previous work, 120 thermodynamic graphs
Xia Zhao, Yi-Lin Hou, Jun Yang, Xin-Hua Wang, Chong-Shan Hu, Xiao-Qing Zhu, Guang-Bin Shen   +6 more
doaj   +1 more source

Atomic Size Misfit for Electrocatalytic Small Molecule Activation

Advanced Functional Materials, EarlyView.
This review explores the application and mechanisms of atomic size misfit in catalysis for small molecule activation, focusing on how structural defects and electronic properties can effectively lower the energy barriers of chemical bonds in molecules like H2O, CO2, and N2.
Ping Hong, Changfan Xu, Huaping Zhao, Yong Lei   +3 more
wiley   +1 more source

Valence Tautomerism in Chromium Half-Sandwich Triarylmethylium Dyads

Inorganics, 2023
Valence tautomerism (VT) may occur if a molecule contains two chemically different redox-active units, which differ only slightly in their intrinsic redox potential.
Anja Rehse, Michael Linseis, Mykhailo Azarkh, Malte Drescher, Rainer F. Winter   +4 more
doaj   +1 more source

Probing the mechanism of electron capture and electron transfer dissociation using tags with variable electron affinity [PDF]

, 2009
Electron capture dissociation (ECD) and electron transfer dissociation (ETD) of doubly protonated electron affinity (EA)-tuned peptides were studied to further illuminate the mechanism of these processes. The model peptide FQpSEEQQQTEDELQDK, containing a
Beauchamp, J. L., Chung, Cheol K., Loo, Joseph A., Ramachandran, Prasanna, Sohn, Chang Ho, Yin, Sheng   +5 more
core   +2 more sources

Copper‐based Materials for Photo and Electrocatalytic Process: Advancing Renewable Energy and Environmental Applications

Advanced Functional Materials, EarlyView.
Cu‐based catalysts as a cornerstone in advancing sustainable energy technologies are fully reviewed in this manuscript, highlighting their potential in photo‐ and electrocatalysis. It includes metallic copper, copper oxides, copper sulfides, copper halide perovskites, copper‐based metal–organic frameworks (MOFs), and covalent organic frameworks (COFs),
Jéssica C. de Almeida, Yanjie Wang, Thais A. Rodrigues, Paulo H. H. Nunes, Vagner R. de Mendonça, Paulo H. E. Falsetti, Leticia V. Savazi, Tao He, Alexandra V. Bardakova, Aida V. Rudakova, Jie Tian, Alexei V. Emeline, Osmando F. Lopes, Antonio Otavio T. Patrocínio, Jia Hong Pan, Caue Ribeiro, Detlef W. Bahnemann   +16 more
wiley   +1 more source

Hydrogen-atom abstractions: a semi-empirical approach to reaction energetics, bond lengths and bond-orders [PDF]

Journal of the Chemical Society, Perkin Transactions 2, 1998
We propose the use of the Intersecting-State Model (ISM) to estimate activation barriers and reactive bond distances for reactions involving the transfer of hydrogen atoms. The method is used in a variety of systems with transition states of the (H)C-H-C(H), N-H-C(H), O-H-C(H), S-H C(H), Si-H-C, Si-H-Si, Sn-H-C and Ge-H-C types.
Pais, Alberto A. C. C., Arnaut, Luís G., Formosinho, Sebastião J.   +2 more
openaire   +3 more sources