On the Nature of Improper Hydrogen Bonding in RCH<sub>2</sub>F and RCHF<sub>2</sub> Motifs. [PDF]
Angew Chem Int Ed EnglPiscelli BA +3 more
europepmc +1 more source
Beyond the Edge: Charge‐Transfer Excitons in Organic Donor‐Acceptor Cocrystals
Advanced Functional Materials, EarlyView.Complex excitonic landscapes in acene–perfluoroacene cocrystals are unveiled by polarization‐resolved optical spectroscopy and many‐body theory. This systematic study of a prototypical model system for weakly interacting donor–acceptor compounds challenges common views of charge‐transfer excitons, providing a refined conceptual framework for ...
Sebastian Anhäuser +6 more
wiley +1 more source
Synthesis, characterization, and hydrogen bonding analysis of copper complexes with acetate bridging: insights into interactions in crystal networks. [PDF]
Sci RepMirtamizdoust B +4 more
europepmc +1 more source
Triplet‐Triplet Annihilation Enhances Photochemical Curing Contrast for Vat‐Based 3D Printing
Advanced Functional Materials, EarlyView.Triplet–triplet annihilation photopolymerization (TTAP) resins enhance curing contrast for digital light processing (DLP) 3D printing compared to conventional Type I and II photopolymerizations at matched optical densities. By exploiting a superlinear initiation response, TTAP preserves fine details, allowing reliable fabrication of complex structures ...
Connor J. O'Dea +2 more
wiley +1 more source
Ω-Loop mutations control dynamics of the active site by modulating the hydrogen-bonding network in PDC-3 β-lactamase. [PDF]
ElifeChen S +5 more
europepmc +1 more source
Advanced Functional Materials, EarlyView.The carbon cloth electrode with targeted pyridinic nitrogen doping, achieved via urea pyrolysis, effectively modulates the adsorption of Cr(II) species and enhances electron transfer, leading to significantly improved kinetics of the Cr(II)/Cr(III) reaction. The material demonstrates a high discharge capacity of 689.3 mAh and an energy efficiency of 72.
Jinfeng Yi +9 more
wiley +1 more source
Hydrogen Bonding in Chloro- and Hydroxy-7-Azaindoles: Insights from X-Ray, Vibrational Spectroscopy, and DFT Studies. [PDF]
MoleculesDysz K +4 more
europepmc +1 more source
Advanced Functional Materials, EarlyView.Reprogrammable multi‐material smart textiles knitted from liquid crystal elastomer fibers undergo 2D and 3D deformation under thermal and photo stimuli. Circularly knitted tubular structures reversibly contract in radial and axial directions, enabling autonomous climbing, liquid release, and micro pumping.
Xue Wan +8 more
wiley +1 more source
Coordination-Driven Orthogonal Ligand Pairings through Dual Hydrogen-Bonding/π-π Interaction Complementarity. [PDF]
ChemistrySmith JN +4 more
europepmc +1 more source
Advanced Functional Materials, EarlyView.We report a polymer‐chain insertion strategy to fabricate pore‐threaded MOF thin films with precisely tuned surface chemistry and wettability. Grafting n‐alkane chains into the pillared layer Cu2(bdc)2(dabco) MOF thin film's vertical nanochannels enhances water stability, and induces hydrophobicity and lubricant‐free, solid‐like slippery behavior ...
Angana Borbora +4 more
wiley +1 more source