Results 101 to 110 of about 38,709 (289)

Borylcyclopropanes: Synthetic Strategies and Applications

open access: yesAngewandte Chemie, EarlyView.
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley   +2 more sources

Formation of some heterocycles based on hydrogen cyanide [PDF]

open access: yes, 1996
Cyanogen chloride (prepared from hydrogen cyanide) has been used to prepare chlorosulfonyl isocyanate which cab be adopted as the starting material in syntheses of N-methyl-N-phenyl-sulfuric diamides whose ortho derivates are cyclized to give substituted
Kaválek, Jaromír   +3 more
core  

Oxidative Treatment of Cyanide in Wastewater Using Hydrogen Peroxide and Homogeneous Catalyst [PDF]

open access: yes, 2018
Batch kinetic tests were conducted to determine the effects of experimental conditions and catalysts on cyanide degradation. Cyanide degradation by hydrogen peroxide was found to follow first-order kinetics.
김동수
core   +1 more source

Reaction Environment Engineering for Selective C3+ Formation in CO2 Electroreduction: Progress and Perspectives

open access: yesAngewandte Chemie, EarlyView.
This work focuses on how to improve the selectivity and activity of electrocatalytic CO2 reduction to C3+ products, by the integration of electrocatalyst and electrolyte co‐design. We summarize key C3+ formation mechanisms and provide a comprehensive reaction network through thermodynamic analysis.
Ling Chen, Damien Voiry, Yan Jiao
wiley   +2 more sources

Effect of exogenous ectoines on some antifungal activity of Pseudomonas fluorescens UTPF5 under salt conditions

open access: yesBiological Journal of Microorganism, 2016
Introduction: Plant probiotic bacteria like fluorescent pseudomonads are worldly used against soil-borne pathogens through mechanisms such as production of bacterial metabolites and enzymes.
Arghavan Kamaly   +3 more
doaj  

2-(4-Methoxy-1H-indol-3-yl)acetonitrile

open access: yesActa Crystallographica Section E, 2012
In the title compound, C11H10N2O, the cyanide group is twisted away from the indole-ring plane [Ccy—Cme—Car—Car = 70.7 (2)°; cy = cyanide, me = methylene, ar = aromatic], whereas the methoxy C atom is ...
Yong-Hong Lu, Mei-Ling Pan, Yang-Hui Luo
doaj   +1 more source

Water‐Dispersible Ruthenium Nanocatalyst for Carbonyl Reduction With D2 or T2 in Aqueous Media

open access: yesAngewandte Chemie, EarlyView.
We report the synthesis and characterization of water‐dispersible ruthenium nanoparticles that catalyze the reductive deuteration and tritiation of carbonyl compounds in aqueous media, enabling efficient access to a broad range of isotopically labeled polar molecules, including cyclic peptides, antibody‐drug conjugate linkers, pegylated derivatives ...
Elisa Martinelli   +6 more
wiley   +2 more sources

Cobalt‐Catalyzed Radical Ligand Transfer (RLT) Enables Remote‐Markovnikov Hydroamination of Alkenes

open access: yesAngewandte Chemie, EarlyView.
A cobalt‐catalyzed remote‐Markovnikov 1,3‐hydroamination of allyl carboxylates proceeds through MHAT, 1,2‐radical acyloxy migration (1,2‐RAM), and radical ligand transfer (RLT) from a Co‐N intermediate, providing protected amino alcohols. ABSTRACT Amino alcohols are prevalent in pharmaceuticals, agrochemicals, and functional materials, yet ...
Arman Khosravi   +7 more
wiley   +2 more sources

Crystal structure of 2-(4-chlorophenyl)-4-(1H-indol-3-yl)-6-phenylpyridine-3-carbonitrile

open access: yesActa Crystallographica Section E, 2014
In the title compound, C26H16ClN3, the dihedral angles between the central pyridine ring and the pendant phenyl, chlorobenzene and indole rings are 18.52 (12), 48.97 (11) and 21.20 (10)°, respectively.
R. Vishnupriya   +4 more
doaj   +1 more source

Hydrogen Cyanide Fumigation

open access: yesBotanical Gazette, 1919
1. Different concentrations of hydrocyanic acid gas gave effects ranging from stimulative to depressive. The maximum of beneficial results was secured from concentrations deadly to insect life, but just a little below the point of first injury to the plant. 2.
openaire   +2 more sources

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