Carbon Energy, EarlyView.Replacing the oxygen evolution reaction with the electro‐oxidation of pollutants and waste streams offers an energy‐efficient route for simultaneous hydrogen production and pollutant remediation. This review summarizes the reaction mechanisms, catalyst design principles, and emerging paired‐electrolysis strategies that govern activity, selectivity ...
Safa Al‐Yahyaey +4 more
wiley +1 more source
Harnessing Hydrogen Cyanide (HCN): Responsive Chemical Tools for Delivering an Emerging Gasotransmitter. [PDF]
Angew Chem Int Ed EnglPluth MD.
europepmc +1 more source
Applications of Biomaterials in Separators for Secondary Batteries
Carbon Energy, EarlyView.In this review, biomaterial‐based separators are reviewed as sustainable alternatives to conventional polyolefin‐based separators. For 12 different natural polymers, spanning from Protista, Plantae, and Animalia, viable strategies for synthesizing biomass‐based separators are described.
Jongyoung Choi +3 more
wiley +1 more source
Reduction of Hydrogen Cyanide in Cassava Peel With Sodium Bicarbonate and Heating Using a Stirrer Chamber Unit. [PDF]
ScientificWorldJournalNarwati, Setiawan, Hadi S.
europepmc +1 more source
Expanding Cyanide‐Bridged Weakly Coordinating Anions Through the Brominated Silver Salt Ag[BCNBBr]
Chemistry – A European Journal, EarlyView.The brominated weakly coordinating anion [μ‐(CN)(B(C6F4Br)3)2] ([BCNBBr]−), based on two B(C6F4Br)3 units bridged by cyanide, is obtained as its silver salt Ag[BCNBBr] from CH2Cl2. Ag[BCNBBr] enables oxidation and halide abstraction reactions, affording diverse [BCNBBr]− salts with oxidizing and electrophilic cations.
Amina L. Moshtaha +4 more
wiley +1 more source
Stereochemical Control in the Matteson Reaction
Chemistry – A European Journal, EarlyView.The Matteson homologation is a highly versatile method for the stereoselective insertion of carbenoids into boronic esters. Through iterative application of the process, complex chiral molecules can be synthesized. The stereoselectivity of the reaction is determined by a chiral diol incorporated in the boronic ester.
Hae Mo Lee, Christoph Hirschhäuser
wiley +1 more source
Photo-amygdalin: light-dependent control over hydrogen cyanide release and cytotoxicity. [PDF]
Chem SciSchulte AM +4 more
europepmc +1 more source
Chemistry – A European Journal, EarlyView.Cyclopropylamines have emerged as powerful photocatalytic building blocks. Upon light‐induced single‐electron oxidation, they undergo strain‐release ring opening to generate distonic iminium radicals that enable diverse transformations, including ring‐opening functionalization, formal [3 + 2] cycloadditions, radical cascades, and asymmetric bond ...
Maria Chiara Cabua +3 more
wiley +1 more source
Multifaceted Evaluation of <i>Paliurus spina-christi</i> Mill. Plant, Seeds, and Oils: Hydrogen Cyanide, Phytochemical, Bioactive, and Antimicrobial Insights from Türkiye Ecotypes. [PDF]
MoleculesÇelebi RS, Duman E.
europepmc +1 more source
Deriving General Energy Predictors for Pnictogen Bonding
Chemistry – A European Journal, EarlyView.This study derives general energetic predictors for pure pnictogen bonds from nitrogen to bismuth based on the potential energy density at the bond critical point. The research highlights the increasing occurrence of secondary interactions for heavier elements.
Jan Langwald, Antonio Frontera
wiley +1 more source