Photochemical Reaction Mechanism of Phosphapropyne to Ethynylphosphinidene via Sequential Hydrogen Atom Transfers and Dehydrogenation. [PDF]
Mu D, Li QS.
europepmc +1 more source
We investigate size‐dependent CO selectivity on Ag nanoparticles, where optimized Ag loading achieves nearly 100% Faradaic Efficiency for CO at −100 mA·cm−2. In situ SERS and XPS reveal the crucial role of optimized loading in catalytic performance. The Ag/C catalyst further exhibits bifunctional activity, enabling efficient electrolysis of CO2 and ...
Venkata S. R. K. Tandava +16 more
wiley +1 more source
Polyphenols at the Helm: Excited State Photophysics and Mechanistic Insights Into Protein-Aggregation Inhibition Through Ultrafast Studies. [PDF]
Majumdar S +7 more
europepmc +1 more source
Stereometric Molecular Engineering for Ultra‐Stable Aqueous Zinc‐Ion Batteries
Stereochemical configuration of molecular additives greatly influences interfacial adsorption at the Zn surface. The optimal tilted dual‐anchored adsorption geometry of myo‐inositol constructs a water‐deficient interface and regulates the solvation structure.
Cunxin Liu +4 more
wiley +1 more source
Borylation of Aryl Halides Induced by Visible Light Under Open-To-Air Environment. [PDF]
Herrera-Luna JC +5 more
europepmc +1 more source
Covalent Functionalization of 2D Semiconductors: A Roadmap to Advanced Electronic Devices
This Review presents recent advances in the covalent functionalization strategies for two‐dimensional semiconductors and their implementation in modern technologies. Layered materials are modified through diverse molecular chemistries (e.g., thiols, diazonium salts, alkyl halides, and electron‐deficient species) to tailor their surface properties ...
Ramiro Quirós‐Ovies +2 more
wiley +1 more source
Electronic and solvent reorganization in proton-coupled electron transfer captured by ultrafast X-rays. [PDF]
Kahraman A +26 more
europepmc +1 more source
This work reveals the UV‐curing‐induced monomer‐rich domain, oligomer‐rich domain, and entangled oligomer domain. The cured submicron films in stressed state induce interlayer nano‐wrinkle structures during the deposition of the second layer. Stress‐free cured films in relaxed state form non‐diffusive, diffusive and semi‐diffusive interlayer ...
Shouzheng Chen +13 more
wiley +1 more source
Excited-state conformational flexibility enables intrinsic amplification of circularly polarized luminescence. [PDF]
Jin JN, Zhang RL, Liao R, Wang F.
europepmc +1 more source
Atomically dispersed Ni–S4 sites on CdS nanorods induce interfacial charge polarization, directing photogenerated electrons to H2 evolution and holes to selective ester‐bond cleavage of poly(lactic acid). Without sacrificial reagents, this charge‐coupled system produces lactate while suppressing overoxidation, achieving an H2 evolution rate of 41.74 ...
Yu Yao +8 more
wiley +1 more source

