Results 31 to 40 of about 56,968 (297)

Mass spectrometric measurement of hydrogen isotope fractionation for the reactions of chloromethane with OH and Cl [PDF]

open access: yesAtmospheric Chemistry and Physics, 2018
Chloromethane (CH3Cl) is an important provider of chlorine to the stratosphere but detailed knowledge of its budget is missing. Stable isotope analysis is a potentially powerful tool to constrain CH3Cl flux estimates.
F. Keppler   +11 more
doaj   +1 more source

Temperature dependence of hydrogen isotope effect in LaNi5-H(D) system

open access: yesNuclear Analysis, 2023
To study inverse effect of hydrogen isotopes in LaNi5 for hydrogen isotope separation at ambient temperature, temperature dependence of hydrogen isotope effect in LaNi5-H(D) system was investigated in the temperature range -70 °C to 3 °C.
Weiwei Wang   +6 more
doaj   +1 more source

The effectiveness of using carbonate isotope measurements of body tissues to infer diet in human evolution: Evidence from wild western chimpanzees (Pan troglodytes verus)* [PDF]

open access: yes, 2015
Changes in diet throughout hominin evolution have been linked with important evolutionary changes. Stable carbon isotope analysis of inorganic apatite carbonate is the main isotopic method used to reconstruct fossil hominin diets; to test its ...
Boesch, Christophe   +7 more
core   +1 more source

Isotope Effects on Chemical Shifts in the Study of Intramolecular Hydrogen Bonds

open access: yesMolecules, 2015
The paper deals with the use of isotope effects on chemical shifts in characterizing intramolecular hydrogen bonds. Both so-called resonance-assisted (RAHB) and non-RAHB systems are treated. The importance of RAHB will be discussed.
Poul Erik Hansen
doaj   +1 more source

Empirical evidence for the fractionation of carbon isotopes between diamond and iron carbide from the Earth’s mantle [PDF]

open access: yes, 2014
S.M. would like to thank the Engineering and Physical Sciences Research Council, the Diamond Trading Company, and the Department of Physical Sciences, The Open University (UK) for financial support during his time as a PhD student at University College ...
Krispin, Catherine   +16 more
core   +1 more source

Origin and pathways of pro- and retrograde fluids, PTt paths and fluid-mineral equilibria from Alpine veins of the Central Alps : case studies of the Fibbia and Amsteg areas [PDF]

open access: yes, 2006
In order to constrain the conditions of and processes related to vein formation and the origins of mineralising fluids, field work, multiple geochemical methods applied to whole rocks, minerals, and fluid inclusions, as well as thermodynamic modeling ...
Heijboer, Tjerk Cornelis
core   +1 more source

Quantitative Prediction of Selectivity in Iridium-Catalysed Hydrogen Isotope Exchange Reactions [PDF]

open access: yes, 2020
A pallette of commonly used directing groups, including various pharmaceutically relevant nitrogen-containing heterocycles, are quantitatively ranked based on the results of intermolecular hydrogen isotope exchange competition reactions using two iridium
William, Kerr   +3 more
core   +1 more source

Periodicity in the isotope chemistry of hydrogen [PDF]

open access: yesProceedings of the National Academy of Sciences, 1981
Periodicities and regularities are established among the deuterium to protium isotopic reduced partition function ratios, ln( s / s ′) f , of 39 diatomic and 19 polyatomic hydrides. It is shown that ln( s / s ′)
openaire   +2 more sources

The isotopic composition of methane in the stratosphere : high-altitude balloon sample measurements [PDF]

open access: yes, 2011
The isotopic composition of stratospheric methane has been determined on a large suite of air samples from stratospheric balloon flights covering subtropical to polar latitudes and a time period of 16 yr.
Brass, Marc   +11 more
core   +1 more source

Bifunctional catalytic activity of anion-doped LaSrCoO4 for oxygen reduction and evolution reactions

open access: yesRoyal Society Open Science
Here, we synthesized Co-based, anion-incorporated‍ ‌R‌u‌d‌d‌l‌e‌s­d‌e‌n‌–‌Popper perovskite electrocatalysts (LaSrCoO4−x X y ) and compared their catalytic performances in the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER).
Ittoku Nozawa, Hidehisa Hagiwara
doaj   +1 more source

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