Results 181 to 190 of about 19,638 (264)

Maximizing Active Site Density in Tin Single‐Site Catalysts for Selective Carbon Dioxide to Formate Electroreduction

open access: yesAngewandte Chemie, EarlyView.
High‐loading tin single‐site catalysts (>7.5 wt.% Sn) are synthesized using a nitrogen‐enriched carbon scaffold and mechanochemically assisted pyrolysis to stabilize atomically dispersed Sn. The resulting Sn/N‐C‐M catalyst enables highly selective CO2‐to‐formate conversion (>90% FE across 50–500 mA cm−2) with long‐term durability and operando‐verified ...
Katharina Potemkin   +12 more
wiley   +1 more source

Metal–Metal Cooperative C─F and S─F Bond Cleavage by Low‐Valent Tetracobalt Clusters and Water‐Assisted Fluoroarene Hydrodefluorination

open access: yesAngewandte Chemie, EarlyView.
Self‐assembled tetrahedral CoI4 clusters supported by simple bipyridine‐based ligands undergo core rearrangement to cleave S─F and C(sp2)─F bond, forming fluoride‐bridged tetracobalt(II)‐oxo clusters, while exposure of cobalt(I) clusters to molecular oxygen yields cubane‐type cobalt(III) oxo clusters.
Hoan M. Dinh   +4 more
wiley   +1 more source

Global Soil Water Stable Isotope Dataset. [PDF]

open access: yesSci Data
Yang J   +17 more
europepmc   +1 more source

Gain‐of‐Function Engineering of the NifEN Scaffold Into a Self‐Assembling Nitrogenase

open access: yesAngewandte Chemie, EarlyView.
From scaffold to enzyme: Systematic engineering of the cofactor maturation scaffold NifEN reconstructs the P→M electron relay along with cofactor coordination and proton gating at the S2B site, converting NifEN into a functional nitrogenase capable of ATP‐dependent N2 reduction both in vitro and in vivo.
Yimo Yang   +4 more
wiley   +1 more source

Induction of Methuosis in Breast Cancer Stem Cells by a Cobalt(III) Complex Evokes Immunotherapeutic Response

open access: yesAngewandte Chemie, EarlyView.
Cancer stem cells (CSCs) drive metastasis, relapse and resist conventional apoptosis‐inducing chemotherapies. We report a cobalt(III)‐cyclam complex with pyrene and diflunisal moieties that reduces the viability of breast CSCs at low micromolar concentrations.
Jiaxin Fang   +7 more
wiley   +1 more source

Nitrogen and Sulfur Assimilation in Fish Otoliths Evaluated by Stable Isotope Labeling and NanoSIMS Analysis. [PDF]

open access: yesRapid Commun Mass Spectrom
Hsu HS   +6 more
europepmc   +1 more source

Synergy Between Photon‐to‐Phonon Pathway and Active Lattice Oxygen Enables Efficient and Stable Syngas Synthesis

open access: yesAngewandte Chemie, EarlyView.
This work reports the design of a multifunctional MnOx support coupled with classic Rh catalytic centers for light‐driven dry reforming of methane. Benefiting from efficient photon‐to‐phonon conversion pathway and a dynamic OL‐OV cycle, the catalyst achieves high syngas production rates and light‐to‐chemical energy efficiency without external heating ...
Chengzhi Guo   +11 more
wiley   +1 more source

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