Results 231 to 240 of about 1,812,757 (349)

Nonheme Fe Enzyme‐Catalyzed Enantiodivergent Nitrogen Migration: Directed Evolution and Computational Study of Isopenicillin N Synthases for Biocatalytic Synthesis of Arylglycines

open access: yesAngewandte Chemie, EarlyView.
Nonheme Fe enzyme isopenicillin N synthase was reprogrammed and evolved as an efficient nitrogen migratase IPNSNim, converting diverse azanyl esters to valuable l‐arylglycines with up to 16 000 TTN and 97:3 e.r. IPNSNim and ACCONim allowed enantiodivergent preparation of both l‐ and d‐arylglycines.
Ken Lin   +7 more
wiley   +1 more source

Observation of proton tunneling correlated with phonons and electrons in Pd. [PDF]

open access: yesSci Adv
Ozawa T   +5 more
europepmc   +1 more source

Salt Cluster With Surface Defect Shows Anomalous Acid–Base Chemistry

open access: yesAngewandte Chemie International Edition, EarlyView.
The acid displacement of formic acid in sea‐salt aerosols, releasing HCl, challenges conventional acid–base chemistry. Our gas‐phase experiments show that this reaction occurs on pure NaCl cluster ions in the absence of water. Surface defects of the NaCl cluster ions enable this reaction via enhanced electrostatic interactions of the salt ions with the
Jessica C. Hartmann   +7 more
wiley   +1 more source

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