Results 251 to 260 of about 1,812,757 (349)

Intermolecular Enantioselective Nickel‐Catalyzed Arylation of Un‐Activated C(sp3)─H Bond

open access: yesAngewandte Chemie International Edition, EarlyView.
Ni: a new solution for asymmetric C(sp3)─H activation. The stereoselective synthesis of all‐carbon quaternary stereogenic centres is achieved via enantioselective C(sp3)─H arylation using a Ni‐BINOL‐derived catalyst. Rational catalytic cycle design uncovers a new reaction pathway that can efficiently induce chiral information during the stereoselective
Erwan Brunard   +4 more
wiley   +1 more source

Separation of Hydrogen Isotopes

open access: yesPlatinum Metals Review, 1957
openaire   +1 more source

δ(<sup>18</sup>O/<sup>16</sup>O) Determinations in Water Using Inductively Coupled Plasma-Tandem Mass Spectrometry. [PDF]

open access: yesAnal Chem
Lancaster ST   +10 more
europepmc   +1 more source

Structural Revision of the C16 Sesquiterpene Hegelenether and the Mechanism of C6‐Methylation in Terpene Biosynthesis

open access: yesAngewandte Chemie International Edition, EarlyView.
The structure of the non‐canonical C16 sesquiterpene named hegelenether was revised to the structure of marxdiol, and its absolute configuration was assigned. Isotopic labeling experiments revealed the stereochemical course of the methyltransferase involved in its biosynthesis.
Heng Li   +3 more
wiley   +1 more source

Radium Speciation in Simulated Digestive Biofluids: Insights from Electrospray Ionization Mass Spectrometry and Thermodynamic Modeling

open access: yesAnalysis &Sensing, EarlyView.
Electrospray ionization mass spectrometry (ESI‐MS) combined with thermodynamic modeling provides the first direct characterization of radium speciation in synthetic gastrointestinal biofluids. Free Ra2+ ions predominate with minimal protein binding and negligible EDTA complexation. Crown ethers enable effective Ra complexation.
Linus Holtmann   +5 more
wiley   +1 more source

Innovative Approach to Hydrogen Purification: A Review on the Role of Metal Hydrides

open access: yesAsia-Pacific Journal of Chemical Engineering, EarlyView.
ABSTRACT Metal hydrides, renowned for their unique hydrogen bonding capabilities, have emerged as pivotal materials in the energy sector, particularly for hydrogen storage and purification applications. Their ability to store hydrogen reversibly under moderate conditions has positioned them at the forefront in hydrogen‐based energy systems. This review
T. Mohammed Faheem   +4 more
wiley   +1 more source

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