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In Situ Amine Formation to Modulate MOF‐Derived PdIn N‐Doped Carbon Catalysts

open access: yesAdvanced Materials, EarlyView.
An amine‐assisted approach converts PdIn‐MOF into PdIn intermetallic nanoparticles embedded in N‐doped carbon. In situ‐generated amines trigger early Pd nucleation, producing smaller PdIn domains than direct pyrolysis. Amine sterics and basicity tune composition and particle size, while solvent and amine co‐determine textural features.
Gonzalo Egea   +9 more
wiley   +1 more source
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HYDROGEN STORAGE

Hydrogen is difficult to store and carry because hydrogen is a gas under ambient conditions. Thus, hydrogen storage in liquid or solid form has attracted significant attention. Hydrogen is converted to hydrogen peroxide by reaction with dioxygen with an appropriate catalyst. Hydrogen peroxide is used as a fuel in a membraneless one-compartment hydrogen
Peter Ozaveshe Oviroh   +4 more
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