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Physical Chemistry Chemical Physics, 2003
The thermodynamics of the hydrophobic effect, as measured primarily through the temperature dependence of solubility, is reviewed, and then a class of models that incorporate the basic mechanism of hydrophobicity is described. These models predict a quantitative relation between the free energy of hydrophobic hydration and the strength of the solvent ...
B. Widom +2 more
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The thermodynamics of the hydrophobic effect, as measured primarily through the temperature dependence of solubility, is reviewed, and then a class of models that incorporate the basic mechanism of hydrophobicity is described. These models predict a quantitative relation between the free energy of hydrophobic hydration and the strength of the solvent ...
B. Widom +2 more
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Current Opinion in Colloid & Interface Science, 1996
Computer simulation and theoretical studies have improved significantly our understanding of the connection between the structural organization of water surrounding hydrophobic solutes and anomalous thermodynamic behavior associated with the ‘hydrophobic effect’.
Michael E Paulaitis +2 more
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Computer simulation and theoretical studies have improved significantly our understanding of the connection between the structural organization of water surrounding hydrophobic solutes and anomalous thermodynamic behavior associated with the ‘hydrophobic effect’.
Michael E Paulaitis +2 more
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Modulation of Hydrophobic Effect by Cosolutes
The Journal of Physical Chemistry B, 2006This work concerns a comparison of the hydration properties and self-association behavior in aqueous solution of three biologically relevant simple molecules: tert-butyl alcohol (TBA), trimethylamine-n-oxide (TMAO), and glycine betaine (GB). These molecules were used as a model to study hydrophobic behavior in water solutions.
DI MICHELE, ALESSANDRO +5 more
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Isotope effects on hydrophobic interaction in hydrophobic polyelectrolytes
Macromolecules, 1985Transition de conformation induite par le pH d'un copolymere alterne acide maleique ...
Nobumichi Ohno, Shintaro Sugai
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UNDERSTANDING THE HYDROPHOBIC EFFECT
Journal of Dispersion Science and Technology, 1994ABSTRACT The hydrophobic effect is the common expression for processes where nonpolar groups in molecules are spontaneously removed from water. Thermodynamic analysis of hydrocarbon solubility in water, micellization and adsorption of surfactants show that the hydrophobic effect can be understood in terms of two contributions. The first contribution is
Bengt Kronberg* +2 more
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