Zirconium-Catalyzed Alkene Hydrophosphination and Dehydrocoupling with an Air-Stable, Fluorescent Primary Phosphine [PDF]
Inorganics, 2016 Zirconium-catalyzed alkene hydrophosphination and dehydrocoupling with an air-stable, fluorescent primary phosphine 8-[(4-phosphino)phenyl]-4,4-dimethyl-1,3,5,7-tetramethyl-2,6-diethyl-4-bora-3a,4a-diaza-s-indacene furnishes fluorescent phosphine ...
Christine A. Bange +7 more
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Room Temperature Ni(II) Catalyzed Hydrophosphination and Cyclotrimerization of Alkynes
Inorganics, 2018 The catalytic activity of nickel complexes in hydrophosphination involving secondary phosphines is not a commonly studied transformation. Beyond a small number of stand-out examples, many reports in the literature focus on the use of simple nickel salts.
Ruth L. Webster
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CYTOP® 366: A Tertiary Phosphine Inaccessible by Most Traditional Hydrophosphination Methods [PDF]
ChemistryOpenHomogenous catalysis is an essential tool within the commercial manufacture of bulk and fine chemicals. Within this, phosphine ligands, such as tricyclohexylphosphine, otherwise known as CYTOP® 366, are a crucial component.
Dr. Dino Amoroso +9 more
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Alkali-Metal Base Catalyzed Electrocyclization of Isoprene Derivatives. [PDF]
ChemistrySimple and abundant alkali‐metal base catalysis in combination with Lewis basic polyamines enables the electrocyclization of isoprene‐derived trienes to cycloheptadienes under neat conditions. Mechanistic insight supported by DFT guides a scalable route to seven‐membered carbocycles which, after reduction, give saturated cycloalkanes relevant as ...
Le Roch M +3 more
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Cyclopropenes in Photochemical Reactions. [PDF]
ChemistryThe photochemical side of cyclopropenes. Cyclopropenes are valuable synthetic tools in organic chemistry. In particular, this review focuses on the photochemistry of cyclopropenes. The reactivity of cyclopropenes excited by irradiation is discussed showing their unique potential for organic synthesis.
Suárez-García D, Coto D, Vicente R.
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A Phosphorus(V)-Centered Porphyrin Having Redox- and Air-Stable Axial P-H Bonds. [PDF]
ChemistryPhosphorus‐centered porphyrins are important functional dyes. Herein, we report the synthesis and characterization of a phosphorus(V) porphyrin complex with hydrogen atoms as axial ligands (1+·PF6–). 1+·PF6– is air‐stable. Cyclic voltammetry of 1+·PF6– exhibits two reversible waves, which indicates sequential redox couples among cationic, neutral open ...
Ishida S +4 more
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Broken Promises? On the Continued Challenges Faced in Catalytic Hydrophosphination [PDF]
ACS Catalysis, 2022 Ruth L Webster +2 more
exaly +2 more sources
A Remarkable Catalyst-Free Photochemical Alkene Hydrophosphination with Bis(trimethylsilyl)phosphonite [PDF]
JACS AuEloïse Bréger +5 more
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Catalyst-Controlled Regio- and Enantioselective Hydrophosphination of α,β-Unsaturated Pyridyl Ketones [PDF]
ACS OmegaWendi Shao +5 more
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Manganese(I)-Catalyzed Asymmetric Hydrophosphination of α,β-Unsaturated Carbonyl Derivatives. [PDF]
Org Lett, 2023 Here we report catalytic asymmetric hydrophosphination of α,β-unsaturated carbonyl derivatives using a chiral Mn(I) complex as a catalyst. Through H–P bond activation, various phosphine-containing chiral products can be accessed via hydrophosphination of
Postolache R +5 more
europepmc +3 more sources