Results 51 to 60 of about 852 (119)
Catalytic Hydrophosphination of Styrenes
, 2016 The first example of intermolecular hydrophosphination of styrenes catalyzed by Ni and Pd complexes is described. The reaction of Ph2PH with styrene, 4-vinylpyridine, 2-vinylpyridine, 4-methoxystyrene, 2-methoxystyrene, and 5-vinyl-2-methylpyridine in ...
Marina A. Kazankova (2731087) +2 more
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1,1-Diphosphines and divinylphosphines via base catalyzed hydrophosphination
, 2018 A catalytic hydrophosphination route to 1,1-diphosphines is yet to be reported: these narrow bite angle pro-ligands have been used to great effect as ligands in homogeneous catalysis.
Coles, N. T. +2 more
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Advanced Synthesis &Catalysis, Volume 367, Issue 24, December 22, 2025.A new strategy for synthesis of P‐chiral phosphines via manganese‐catalyzed enantioselective hydrophosphination was established. The solvent like iPrOH was found to be able to tune the enantioselectivity of the product, thus providing both enantiomers of P(III)‐stereogenic compounds with a single (Rc, Sp)‐Clarke Mn(I) complex catalyst. In this work, we
Bin Wan, Syuzanna R. Harutyunyan
wiley +1 more source
π‐Complexes of Main‐Group Metal Cations: Exploration of Lewis Acid Reactivity
ChemistryEurope, Volume 3, Issue 6, November 11, 2025.A series of cationic main‐group complexes was obtained using the neutral, zwitterionic ligand IDP. The Lewis acidity of these complexes is explored by catalytic hydrophosphinations and halide addition reactions. The latter allow for the isolation of unusual π‐complexes of tetryliumylidenes.
David Zuber, Stefan Frei, Peter Coburger
wiley +1 more source
Challenges in Catalytic Hydrophosphination
, 2016 Despite significant advances, metal-catalyzed hydrophosphination has ample room for discovery, growth, and development. Many of the key successes in metal-catalyzed hydrophosphination over the last decade have indicated what is needed and what is yet to ...
Bange, Christine A., Waterman, Rory
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, 2016 Organolanthanide-Catalyzed Intramolecular Hydrophosphination/Cyclization of Phosphinoalkenes and ...
Tobin J. Marks (1275348) +1 more
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Organocatalytic asymmetric hydrophosphination of nitroalkenes
, 2007 The first direct asymmetric hydrophosphination (AHP) of nitroalkenes has been accomplished. The use of bifunctional cinchona alkaloid catalyst has provided an useful organocatalytic route to optically active β-nitro phosphines (up to 99% ee after ...
MELCHIORRE, PAOLO +13 more
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The role of the M−PR2 fragment in hydrophosphination: from mechanisms to catalysis [PDF]
, 2019 In this thesis, the synthesis and reactivity of metal complexes containing phosphido (PR2−) and phosphenium (PR2+) ligands for the hydrophosphination of alkenes were investigated.
Belli, Roman
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, 2016 An organopalladium complex containing ortho-metalated (S)-(1-(dimethylamino)ethyl)naphthalene as the chiral auxiliary has been used to promote the asymmetric hydrophosphination reactions between diphenylphosphine and (E)- or (Z)-diphenyl-1 ...
Hun-Beng Tan (2700106) +5 more
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Hydrophosphination Substrate Expansion
UndergraduateHydrophosphination is an atom efficient phosphorus-carbon bond synthesizing reaction. Many instances of this reaction in the literature exhibit redundant reagents that fail to show the reaction’s potentially wide range of reactivity. The aim
Tschaikowsky, Peter
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