Results 141 to 150 of about 895 (168)
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Functionality Distribution of Carboxyl- and Hydroxyl-Terminated Polybutadiene
Journal of Macromolecular Science: Part A - Chemistry, 1973Abstract Elurion from silica gel was used to fractionate liquid polymers according to the number of chemically reactive groups per molecule (the functionality). Methods are presented for the functionality fractionation of high and low functionality carboxyl-terminated polybutadiene (CTPB).
M. S. Chang, D. M. French, P. L. Rogers
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Combinations of hydroxyl‐terminated polybutadiene and boron
Journal of Polymer Science: Polymer Chemistry Edition, 1985AbstractMixing and curing experiments with suspensions of boron in hydroxyl‐terminated polybutadiene (HTPB) have been performed. In kneading experiments on a plastograph very high viscous masses with bad curing properties were obtained. The experiments indicated that HTPB is attached with its OH groups to acidic impurities on the surface of the boron ...
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Properties of hydroxyl‐terminated polybutadiene‐urethane systems
Journal of Applied Polymer Science, 1971AbstractThe properties of liquid hydroxyl‐terminated polybutadiene (HTPB) stocks crosslinked with isocyanates of different functionalities were intensively investigated. The stocks were modified by inclusion of small proportions of various low molecular weight diols to increase the urethane concentration. The following studies were carried out: (1) the
John P. Consaga, David M. French
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Polyurethane based on hydroxyl‐terminated polybutadienes
British Polymer Journal, 1971AbstractButadiene has been found to homopolymerise and copolymerise with other reactive vinyl monomers to yield unique liquid polymers which are terminated with reactive allylic hydroxyl groups. Through the use of an isocyanate cure reaction they offer a route to liquid castable general purpose elastomers, capable of reinforcement with various fillers ...
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Functionality distribution and crosslink density of hydroxyl‐terminated polybutadiene
Polymer International, 1993Abstract A novel approach is proposed for estimating the average molecular weight between crosslinks (M̄ c ) from the functionality distribution of hydroxyl‐terminated polybutadiene ( HTPB ). The functionality distribution of four free‐
K. N. Ninan +3 more
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Urethane Elastomers Based on Hydroxyl Terminated Polybutadienes
Journal of Elastoplastics, 1971This article describes the preparation and properties of urethane elastomers based on hydroxyl-terminated polybutadienes. The liquid nature of these polybutadiene systems allows easy reaction with isocyanates even at ambient temperatures. Properties of elastomers produced can be easily improved by either chemical modification of the polymer backbone of
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Polymer, 1994
Abstract Thermal ageing of hydroxyl-terminated polybutadiene propellant binders was carried out at various temperatures between 50 and 100°C. The changes caused by this treatment in properties such as melt viscosity, functional end-groups, molecular weight, tensile strength, elastic modulus and ultimate elongation were examined.
A. Akbaş, S. Aksoy, N. Hasırcı
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Abstract Thermal ageing of hydroxyl-terminated polybutadiene propellant binders was carried out at various temperatures between 50 and 100°C. The changes caused by this treatment in properties such as melt viscosity, functional end-groups, molecular weight, tensile strength, elastic modulus and ultimate elongation were examined.
A. Akbaş, S. Aksoy, N. Hasırcı
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Catalysis of Blocked Isocyanate-Hydroxyl-Terminated Polybutadiene Cure Reaction
Journal of Macromolecular Science, Part A, 1996The catalytic activity of three tertiary amines and three organotin compounds in the cure reaction of blocked isocyanate with hydroxyl-terminated polybutadiene was investigated. It was found that the steric factor determines the catalytic activity of the compound. The tin compounds showed higher catalytic activities than the amine compounds.
H. Kothandaraman +2 more
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Thermokinetic studies of polyurethanes based on hydroxyl-terminated polybutadiene prepolymer
Journal of Thermal Analysis and Calorimetry, 2017Three different polyurethane compositions were prepared based on hydroxyl-terminated polybutadiene (HTPB) prepolymer with different curative types. The employed curatives were hexamethylene diisocyanate (HMDI), isophorone diisocyanate (IPDI) and dicyclohexylmethane-4,4'-diisocyanate.
Sameh A. El-Basuony +3 more
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