Results 111 to 120 of about 966,330 (294)

Hydroxyl radical reaction with monuron [PDF]

open access: yes, 2015
On the example of monuron, aromatic ring hydroxylation reactions were studied by Density Functional Theory calculations. In order to model the aqueous media the Solvation Model Density technique was used.
Wojnárovits László   +6 more
core  

Photo‐Switchable Molecular Module Programming PET Biodegradation in Aquatic Environments

open access: yesAdvanced Functional Materials, EarlyView.
We address the plastic durability paradox by integrating an itaconic acid–derived pyrrolidone module into polymer backbones. Sunlight in water triggers Norrish Type I ring‐opening and hydrophilization, enabling rapid biodegradation into nontoxic minerals.
Mohammad Asif Ali   +16 more
wiley   +1 more source

Title on signature form: Hydroxyl radical addition to arenes

open access: yes, 2015
Anthropogenic input of organic compounds into aqueous environments and the effects of these contaminants on ecosystems, as well as human health are of great concern.
Moores, Lee C.
core  

How Solvent Modulates Hydroxyl Radical Reactivity in Hydrogen Atom Abstractions

open access: yes, 2016
The hydroxyl radical (HO•) is a highly reactive oxygen-centered radical whose bimolecular rate constants for reaction with organic compounds (hydrogen atom abstraction) approach the diffusion-controlled limit in aqueous solution.
Diego Troya (1687087)   +3 more
core   +1 more source

Architecture‐Driven Functional Coupling in Vertically Aligned Nanocomposites

open access: yesAdvanced Functional Materials, EarlyView.
Vertically aligned nanocomposites define a growth‐engineered architecture in which vertical interfaces, strain fields, defect pathways, and phase connectivity are created simultaneously. This review shows how these architectural features couple ferroic, optical, ionic, electrochemical, and device responses, establishing design rules and open challenges
Md Shatil Islam‐Shanto   +4 more
wiley   +1 more source

Desert Plant Inspired Hierarchical Nanofibrous Membranes for Integrated Solar Desalination and Heavy Metal Remediation

open access: yesAdvanced Functional Materials, EarlyView.
An Alhagi maurorum inspired hierarchical composite membrane (NFCu) was developed by integrating heavy metal remediation and solar‐driven interfacial evaporation in a single platform. Beyond the photothermal effect, a localized photocatalytic process is realized on the CuO surface, deepening the mechanistic understanding of light–matter–water ...
Yuqiong He   +9 more
wiley   +1 more source

From Bulk to Colloidal Nanocrystals: Top‐Down Synthesis of Highly Luminescent Cs2ZrCl6:Te4+ Double Perovskite Nanocrystals for X‐Ray Imaging

open access: yesAdvanced Functional Materials, EarlyView.
Top‐down ultrasonication produces highly emissive Cs2ZrCl6:Te4+ nanocrystals (NCs) with a PLQY of 65%, which is higher compared to that of the NCs synthesized by typical bottom‐up hot‐injection synthesis. The colloidal Cs2ZrCl6:Te4+ NCs have been found to be potential candidates for x‐ray scintillation imaging.
Yang Liu   +12 more
wiley   +1 more source

Stereometric Molecular Engineering for Ultra‐Stable Aqueous Zinc‐Ion Batteries

open access: yesAdvanced Functional Materials, EarlyView.
Stereochemical configuration of molecular additives greatly influences interfacial adsorption at the Zn surface. The optimal tilted dual‐anchored adsorption geometry of myo‐inositol constructs a water‐deficient interface and regulates the solvation structure.
Cunxin Liu   +4 more
wiley   +1 more source

Comparison of radical scavenging properties of gosypol and its derivatives in the reaction with DPPH

open access: yesВісник Харківського національного університету: Серія xімія
Radical scavenging activity of 7,7'-ditosyloxygossypol in reaction with 2,2'-diphenyl-1-piсrylhydrazyl (DPPH) in ethanol was evaluated by total stoichiometries and EC50 values.
Oleksii Dykun   +3 more
doaj   +1 more source

Covalent Functionalization of 2D Semiconductors: A Roadmap to Advanced Electronic Devices

open access: yesAdvanced Functional Materials, EarlyView.
This Review presents recent advances in the covalent functionalization strategies for two‐dimensional semiconductors and their implementation in modern technologies. Layered materials are modified through diverse molecular chemistries (e.g., thiols, diazonium salts, alkyl halides, and electron‐deficient species) to tailor their surface properties ...
Ramiro Quirós‐Ovies   +2 more
wiley   +1 more source

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