Results 61 to 70 of about 101 (88)
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Thermochimica Acta, 2018
Abstract The isothermal curing kinetics of hydroxyl-terminated polybutadiene (HTPB) binder system containing dioctyl sebacate (DOS) and polyaryl polyisocyanate (PAPI) was investigated by microcalorimetry. The curing was completed after 5.3 × 105, 4.2 × 105, 3.6 × 105, and 3.2 × 105 s at 303.15, 313.15, 323.15, and 333.15 K, respectively.
Yiyi Xiao +6 more
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Abstract The isothermal curing kinetics of hydroxyl-terminated polybutadiene (HTPB) binder system containing dioctyl sebacate (DOS) and polyaryl polyisocyanate (PAPI) was investigated by microcalorimetry. The curing was completed after 5.3 × 105, 4.2 × 105, 3.6 × 105, and 3.2 × 105 s at 303.15, 313.15, 323.15, and 333.15 K, respectively.
Yiyi Xiao +6 more
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Journal of Applied Polymer Science, 2002
AbstractSolid composite propellants contain 80–90% of a crystalline oxidizer like ammonium perchlorate and powdery metallic fuel like aluminum with 10 to 15% organic binders like HTPB or CTPB, to bind the solids together and maintain the shape under severe stress and strain environment.
B. M. Bandgar +3 more
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AbstractSolid composite propellants contain 80–90% of a crystalline oxidizer like ammonium perchlorate and powdery metallic fuel like aluminum with 10 to 15% organic binders like HTPB or CTPB, to bind the solids together and maintain the shape under severe stress and strain environment.
B. M. Bandgar +3 more
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Journal of Applied Polymer Science, 2011
AbstractWe synthesized a ferrocene‐based burning rate catalyst, 2‐(ferrocenylpropyl) dimethylsilane (FPDS). FPDS‐grafted hydroxyl‐terminated polybutadiene (FPDS‐g‐HTPB) was synthesized using hydrosilylation with a Pt catalyst. The structures of FPDS and FPDS‐g‐HTPB were investigated by Fourier transform infrared spectroscopy and nuclear magnetic ...
Bong‐Sang Cho, Si‐Tae Noh
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AbstractWe synthesized a ferrocene‐based burning rate catalyst, 2‐(ferrocenylpropyl) dimethylsilane (FPDS). FPDS‐grafted hydroxyl‐terminated polybutadiene (FPDS‐g‐HTPB) was synthesized using hydrosilylation with a Pt catalyst. The structures of FPDS and FPDS‐g‐HTPB were investigated by Fourier transform infrared spectroscopy and nuclear magnetic ...
Bong‐Sang Cho, Si‐Tae Noh
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Propellants, Explosives, Pyrotechnics, 1985
AbstractA simple method to evaluate the adhesive force between solid oxidizer and polymeric fuel‐binder is presented. As an illustration, hydroxyl‐terminated polybutadiene (HTPB) sticks including several different bonding agents are bonded on ammonium perchlorate (AP) single crystals, and stress‐strain history until rupture occurs is obtained by ...
K. Hori, A. Iwama, T. Fukuda
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AbstractA simple method to evaluate the adhesive force between solid oxidizer and polymeric fuel‐binder is presented. As an illustration, hydroxyl‐terminated polybutadiene (HTPB) sticks including several different bonding agents are bonded on ammonium perchlorate (AP) single crystals, and stress‐strain history until rupture occurs is obtained by ...
K. Hori, A. Iwama, T. Fukuda
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Journal of Macromolecular Science, Part A, 2017
ABSTRACTA possibility of extending the pot life of the HTPB-TDI based propellant binder system without adverse modification of mechanical properties is explored in the present study. It is proposed that by tailoring functionality distribution of the base HTPB polymer and changing the binder composition concurrently, the pot life of the binder system ...
V. Sekkar +3 more
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ABSTRACTA possibility of extending the pot life of the HTPB-TDI based propellant binder system without adverse modification of mechanical properties is explored in the present study. It is proposed that by tailoring functionality distribution of the base HTPB polymer and changing the binder composition concurrently, the pot life of the binder system ...
V. Sekkar +3 more
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Propellants, Explosives, Pyrotechnics, 2014
AbstractExtension of the pot life for hydroxyl‐terminated polybutadiene (HTPB) based propellant binder systems was attempted through employing a bicurative system comprising of toluene‐di‐isocyanate (TDI) and isophorone‐di‐isocyanate (IPDI). Pot life characteristics were studied through evaluating curing kinetics for the HTPB‐bicurative binder ...
V. Sekkar, Thakur Sudesh Kumar Raunija
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AbstractExtension of the pot life for hydroxyl‐terminated polybutadiene (HTPB) based propellant binder systems was attempted through employing a bicurative system comprising of toluene‐di‐isocyanate (TDI) and isophorone‐di‐isocyanate (IPDI). Pot life characteristics were studied through evaluating curing kinetics for the HTPB‐bicurative binder ...
V. Sekkar, Thakur Sudesh Kumar Raunija
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Progress in Organic Coatings, 2020
Abstract The flow behavior of highly viscous casting explosives in micro-channels and special shaped moulds are critical factors affecting the formations of solid propellants and explosives. In the present work, the spreading property and flow behavior of hydroxyl-terminated polybutadiene (HTPB) binders, a major component of casting explosives, on Cu
Ting Zheng +3 more
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Abstract The flow behavior of highly viscous casting explosives in micro-channels and special shaped moulds are critical factors affecting the formations of solid propellants and explosives. In the present work, the spreading property and flow behavior of hydroxyl-terminated polybutadiene (HTPB) binders, a major component of casting explosives, on Cu
Ting Zheng +3 more
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Journal of Thermal Analysis and Calorimetry, 2020
An energetic composite of an octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine with a polymer matrix is generally developed to reduce sensitivity, improve mechanical strength and furnish engineering shape. A hydroxyl-terminated polybutadiene (HTPB) and various curatives, namely methylene diphenyl diisocyanate (MDI), isophorone diisocyanate (IPDI ...
Rajesh Kumar +4 more
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An energetic composite of an octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine with a polymer matrix is generally developed to reduce sensitivity, improve mechanical strength and furnish engineering shape. A hydroxyl-terminated polybutadiene (HTPB) and various curatives, namely methylene diphenyl diisocyanate (MDI), isophorone diisocyanate (IPDI ...
Rajesh Kumar +4 more
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Journal of Applied Polymer Science, 2003
AbstractIron was coordinately linked to the hydroxyl‐terminated polybutadiene (HTPB) backbone using iron carbonyl via a ligand displacement reaction. The modified HTPB thus obtained was reddish brown in color and was characterized by GPC, FTIR, NMR, thermal, and propellant studies. No significant changes in the rheology, molecular weight, and molecular
K. Subramanian, K. S. Sastri
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AbstractIron was coordinately linked to the hydroxyl‐terminated polybutadiene (HTPB) backbone using iron carbonyl via a ligand displacement reaction. The modified HTPB thus obtained was reddish brown in color and was characterized by GPC, FTIR, NMR, thermal, and propellant studies. No significant changes in the rheology, molecular weight, and molecular
K. Subramanian, K. S. Sastri
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Applied Surface Science, 2019
Abstract The adherent behaviors of hydroxyl-terminated polybutadiene (HTPB), a typical high viscosity liquid widely used as a binder in rocket motor propellants, onto the copper (Cu) surfaces with/without the interference of Al nanoparticles were investigated by classical molecular dynamics (MD) simulations.
Chunya Wu +9 more
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Abstract The adherent behaviors of hydroxyl-terminated polybutadiene (HTPB), a typical high viscosity liquid widely used as a binder in rocket motor propellants, onto the copper (Cu) surfaces with/without the interference of Al nanoparticles were investigated by classical molecular dynamics (MD) simulations.
Chunya Wu +9 more
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