Structural control of a novel hierarchical porous carbon material and its adsorption properties [PDF]
Novel hierarchical porous carbon materials (HPCs) were fabricated via a reactive template-induced in situ hypercrosslinking procedure. The effects of carbonization conditions on the microstructure and morphology of HPCs were investigated, and the ...
Li-Feng Cai +4 more
doaj +2 more sources
Fabrication, Facilitating Gas Permeability, and Molecular Simulations of Porous Hypercrosslinked Polymers Embedding 6FDA-Based Polyimide Mixed-Matrix Membranes [PDF]
Novel polymers applied in economic membrane technologies are a perennial hot topic in the fields of natural gas purification and O2 enrichment. Herein, novel hypercrosslinked polymers (HCPs) incorporating 6FDA-based polyimide (PI) MMMs were prepared via ...
Chaohua Song +9 more
doaj +2 more sources
Hypercrosslinked Polymers for Volatile and Very Volatile Organic Compound Capture Beyond Commercial Benchmarks. [PDF]
The adsorption of volatile and very volatile organic compounds ((V)VOCs) is investigated using hypercrosslinked polymers with varied chemical functionalities. Mixed‐analyte breakthrough experiments reveal how polymer chemistry governs sorption under dry and humid conditions. Amine‐functionalised networks outperform commercial benchmarks, offering broad
Schweng P +3 more
europepmc +2 more sources
Humidity-Induced Self-Oscillating and Self-Healing Hypercrosslinked Metal-Organic Polyhedra Membranes. [PDF]
A new type of hypercrosslinked metal–organic polyhedra (HCMOP) membrane is generated by covalent crosslinking of boronic acid‐modified Zr‐based MOPs with polyvinyl alcohol. Due to the dynamic borate networks, HCMOPs can realize humidity‐induced self‐oscillating and self‐healing properties.
Li J +6 more
europepmc +2 more sources
'Small' Technology, Big Power: Micropore Engineering for High-Performance Flow Battery Membranes. [PDF]
This review systematically analyzes recent advances in redox flow batteries (RFBs) membrane separators, focusing on the shift from traditional ion‐exchange membranes to emerging functional porous membranes: Covalent Organic Frameworks (COFs), Metal‐Organic Frameworks (MOFs), and Polymers of Intrinsic Microporosity (PIMs).
Wei C +7 more
europepmc +2 more sources
Exploiting high‐performance yet low‐cost hard carbon anodes is crucial to advancing the state‐of‐the‐art sodium‐ion batteries. However, the achievement of superior initial Coulombic efficiency (ICE) and high Na‐storage capacity via low‐temperature ...
Yuqian Qiu +10 more
doaj +2 more sources
Best of Both Worlds: Adsorptive Ultrafiltration Nanocellulose-Hypercrosslinked Polymer Hybrid Membranes for Metal Ion Removal. [PDF]
A way to formulate sulfonated hypercrosslinked polymers (SHCPs) into hybrid membranes, a previously difficult task, utilizing a cellulose nanofiber network as a carrier matrix, is reported. The membranes combine the heavy metal adsorption capacity of SHCPs with the ultrafiltration capability of nanopapers, while showing synergistic effects of improved ...
Mayer F +7 more
europepmc +2 more sources
Fundamentals and Design-Led Synthesis of Emulsion-Templated Porous Materials for Environmental Applications. [PDF]
Understanding the structure‐property relationship of materials‐by‐design is very useful to optimize materials predictive functions. Porous materials, especially those prepared via emulsion templating, offer great promise in ubiquitous environmental remediation applications and beyond owing to their interconnected porous structure, enhanced permeability,
Mudassir MA +4 more
europepmc +2 more sources
Nanofibrous Porous Organic Polymers and Their Derivatives: From Synthesis to Applications. [PDF]
In this review, the authors provide a comprehensive overview of porous organic polymers (POPs)‐based nanofibers and their derivatives. The coverage includes synthesis, preparation methodologies, and emerging applications, offering the first exhaustive examination of various nanofibrous POPs, their composite materials, and derived carbon materials ...
Yang C +8 more
europepmc +2 more sources
Hypercrosslinked porous polyporphyrin by metal-free protocol: characterization, uptake performance, and heterogeneous catalysis [PDF]
Through metal-free protocol, hypercrosslinked porous polyporphyrin with permanent porosity was obatined via the Friedel–Crafts alkylation of tetracarbazolylporphyrin using formaldehyde dimethyl acetal as an external cross-linker.
Li-Juan Feng +4 more
doaj +2 more sources

