Hypervalent iodine-mediated intramolecular alkene halocyclisation. [PDF]
Bansal C +3 more
europepmc +1 more source
Fluorophore Design via Generative Modeling in a Curated Subspace. [PDF]
Kim B, Ashyrmamatov I, Ucak UV, Lee J.
europepmc +1 more source
Elucidation of a Parasitic Proton-Coupled Electron Transfer in a Photocatalytic Benzylic C-H Sulfonamidation. [PDF]
Fitzpatrick NA +5 more
europepmc +1 more source
Mediated Electrochemical Oxidation of Nucleosides to Their 5'-Carboxylic Acid Derivatives. [PDF]
Abrams DJ +5 more
europepmc +1 more source
Enantioselective total synthesis of lycoposerramine congeners through late-stage nitrogen deletion. [PDF]
Yokoi K, Renata H.
europepmc +1 more source
The Role of Trifluoromethyl and Trifluoromethoxy Groups in Medicinal Chemistry: Implications for Drug Design. [PDF]
Novás M, Matos MJ.
europepmc +1 more source
Bonding properties and crystal packing in β-(SeCl<sub>4</sub>)<sub>4</sub> derived from Hirshfeld Atom Refinement. [PDF]
Guzmán-Hernández JD, Jancik V.
europepmc +1 more source
Taxonomy of Chemical Bondings: Opportunities and Challenges. [PDF]
Pizzi A +5 more
europepmc +1 more source
Predicting the Stability of Hypervalent Molecules
In this exercise, students use concepts in thermochemistry such as bond energy, ionization potentials, and electron affinities to predict the relative stability of two hypervalent molecules (PF5 and PH5) relative to their respective non-hypervalent counterparts.
Tracy A. Mitchell +2 more
semanticscholar +3 more sources
Chemical Bonding in Hypervalent Molecules: Is the Octet Rule Relevant?
The bonding in a large number of hypervalent molecules of P, As, S, Se, Te, Cl, and Br with the ligands F, Cl, O, CH(3), and CH(2) has been studied using the topological analysis of the electron localization function ELF. This function partitions the electron density of a molecule into core and valence basins and further classifies valence basins ...
Stéphane Noury +2 more
semanticscholar +4 more sources

