[SnF(bipy)(H2O)]2[SnF6], a mixed-valent inorganic tin(II)–tin(IV) compound
Acta Crystallographica Section E: Crystallographic CommunicationsIn the title compound, bis[aqua(2,2′-bipyridine)fluoridotin(II)] hexafluoridotin(IV), [SnF(C10H8N2)(H2O)]2[SnF6], an ionic mixed-valent tin(II)–tin(IV) compound, the bivalent tin atom is the center atom of the cation and the tetravalent tin atom is the ...
Natalia Röwekamp-Krugley, Hans Reuter
doaj +1 more source
Materials Expert-Artificial Intelligence for Materials Discovery [PDF]
arXiv, 2023 The advent of material databases provides an unprecedented opportunity to uncover predictive descriptors for emergent material properties from vast data space. However, common reliance on high-throughput ab initio data necessarily inherits limitations of such data: mismatch with experiments. On the other hand, experimental decisions are often guided by
arxiv
Pulling short DNA molecules having defects on different locations [PDF]
Phys. Rev. E, v92, p03270, 2015, 2015 We present a study on the role of defects on the stability of short DNA molecules. We consider short DNA molecules (16 base pairs) and investigate the thermal as well as mechanical denaturation of these molecules in the presence of defects that occurs anywhere in the molecule. For the investigation, we consider four different kinds of chains.
arxiv +1 more source
Cytoprotective effects of the antioxidant phytochemical indicaxanthin in beta-thalassemia red blood cells [PDF]
, 2006 Antioxidant phytochemicals are investigated as novel treatments for supportive therapy in b-thalassemia. The dietary indicaxanthin was assessed for its protective effects on human b-thalassemic RBCs submitted in vitro to oxidative haemolysis by cumene ...
Allegra, M. +4 more
core +1 more source
Aggregate, EarlyView.The innovation of this work lies in the use of supramolecular interfacial effect of pillararene (CP5) to regulate the performance of CeOx by promoting the charge separation and transportation, which can enhance the SDT efficacy by large ROS generation and TME regulation.
Congcong Wang +6 more
wiley +1 more source
Revisiting the Effect of f-Functions in Predicting the Right Reaction Mechanism for Hypervalent Iodine Reagents [PDF]
arXiv, 2020 To understand the effect of f-functions in predicting the right reaction mechanism for hypervalent iodine reagents, we adopt the Ahlrichs basis set family def2-SVP and def2-TZVP to revisit the potential energy surfaces of IBX-mediated oxidation and Togni I's isomerisation.
arxiv
Exploring the Lewis Acidity and Reactivity of Neutral Pentacoordinate Dithienophospholes.
Chemistry, 2023 A series of luminescent, neutral pentacoordinate dithieno[3,2-b:2',3'-d]phosphole compounds was synthesized by [4+1] cycloaddition of o-quinones with the trivalent corresponding phospholes.
Nayanthara Asok +8 more
semanticscholar +1 more source
\u3cem\u3eN\u3c/em\u3e-Methylbenzothiazole-2(3\u3cem\u3eH\u3c/em\u3e)-selone, C\u3csub\u3e8\u3c/sub\u3eH\u3csub\u3e7\u3c/sub\u3eNSSe [PDF]
, 1997 The crystal structure of N-methyl1,3-benzothiazole-2(3H)-selone, (mbts) has been studied to estimate the changes in the molecular geometry of the mbts ligand upon coordination.
Husebye, Steinar +2 more
core +1 more source
Halogen bonding in hypervalent iodine and bromine derivatives: Halonium salts [PDF]
, 2017 Halogen bonds have been identified in a series of ionic compounds involving bromonium and iodonium cations and several different anions, some also containing hypervalent atoms.
Cavallo, Gabriella +5 more
core +3 more sources
Ruthenium‐Katalysierte ortho‐Arylierung von Benzoesäuren mit Arylthianthreniumsalzen
Angewandte Chemie, EarlyView.Es wurde eine katalytische Ortho‐Arylierungsmethode entwickelt, mit der Arylthianthreniumsalze in Carboxylat‐funktionalisierte Biaryle umgewandelt werden können. Die Carboxylatgruppe kann in situ entfernt oder für eine weitere Derivatisierung verwendet werden.
Kaiping Wang +9 more
wiley +1 more source