Atomic Coordination, Chemical Bonding, and Electronic State of Praseodymium in Pr2Si7
Zeitschrift für anorganische und allgemeine Chemie, Volume 651, Issue 10, July 7, 2025.Pr2Si7 is obtained by high‐pressure, high‐temperature synthesis. The topological coordination numbers underline the significance of the silicon partial structure. The homoatomic connectivity within the polyanionic framework in combination with the formation of lone pairs clearly indicates a hypervalent bonding situation for silicon.
Ulrich Schwarz +5 more
wiley +1 more source
Aggregate, Volume 6, Issue 7, July 2025.The innovation of this work lies in the use of supramolecular interfacial effect of pillararene (CP5) to regulate the performance of CeOx by promoting the charge separation and transportation, which can enhance the SDT efficacy by large ROS generation and TME regulation.
Congcong Wang +6 more
wiley +1 more source
Advances in Mechanochemical C─H Functionalization: A Comparative Study with Solvent‐Based Approaches
ChemCatChem, Volume 17, Issue 13, July 8, 2025.This review presents the latest advancements made in mechanochemical transition metal catalyzed C─H functionalization, comparing its efficiency, sustainability and scope with traditional solvent‐based methods. By offering a side‐by‐side comparison, it equips organic chemists with the insights needed to select the most effective approach for ...
Nanditha Kattukudiyil Narayanan +1 more
wiley +1 more source
Extension of the Polarizable Charge Equilibration Model to Higher Oxidation States with Applications to Ge, As, Se, Br, Sn, Sb, Te, I, Pb, Bi, Po, and At Elements [PDF]
, 2018 We recently developed the Polarizable Charge Equilibration (PQEq) model to predict accurate electrostatic interactions for molecules and solids and optimized parameters for H, C, N, O, F, Si, P, S, and Cl elements to fit polarization energies computed by
Goddard, William A., III +2 more
core +1 more source
Stimuli‐Responsive Optical Materials Based on Hypervalent Antimony‐Containing Conjugated Molecules [PDF]
Kazuya Tanimura +3 more
openalex +1 more source
Diastereoselective Umpolung cyclisation of ketones promoted by hypervalent iodine. [PDF]
Chem SciIannelli G +6 more
europepmc +1 more source
Total Synthesis of (-)-Dimatairesinol via Regioselective Intermolecular Oxidative Phenol Coupling. [PDF]
Org LettChatpreecha R +4 more
europepmc +1 more source
Rh-Catalyzed Enantioselective Aryl C-H Bond Cyclopropylation. [PDF]
J Am Chem SocPalomo E +4 more
europepmc +1 more source
Quadrupolar dinuclear hypervalent tin(iv) compounds with near-infrared emission consisting of Schiff bases based on π-conjugated scaffolds. [PDF]
Chem SciTanimura K, Tanaka K, Gon M, Tanaka K.
europepmc +1 more source