Results 181 to 190 of about 260,704 (287)

Spatially Coupled Cl2 Confinement and Activation at Curved Ni Single‐Atom Sites for Highly Reversible Li–Cl2 Batteries

open access: yesAngewandte Chemie, EarlyView.
A robust cathode featuring curvature‐engineered Ni single‐atoms anchored within hierarchical pores effectively confines Cl2 and accelerates Cl0/Cl−1 redox kinetics. This synergistic architecture unlocks the potential of Li‐Cl2 secondary batteries with an unprecedented 1×106 mAh g−1 cumulative capacity, all‐climate resilience (–40°C to + 70°C), and 7.65
Minggang Xie   +11 more
wiley   +2 more sources

Electrochemically Induced Structural Evolution to Generate Optimized High‐Entropy‐Alloy Electrocatalysts for Ethanol Oxidation

open access: yesAngewandte Chemie, EarlyView.
Electrochemical cycling drives spontaneous facet optimization in high‐entropy Pd@PdPtIrRuRh core‐shell nanocrystals, reshaping simple cubes into severely beveled architectures with balanced {100}/{110}/{111} facets. This dynamic restructuring yields active electrocatalysts that favor complete ethanol oxidation via the C1 pathway, suppress strongly ...
Yueh‐Chun Hsiao   +11 more
wiley   +2 more sources

Synergy Between Photon‐to‐Phonon Pathway and Active Lattice Oxygen Enables Efficient and Stable Syngas Synthesis

open access: yesAngewandte Chemie, EarlyView.
This work reports the design of a multifunctional MnOx support coupled with classic Rh catalytic centers for light‐driven dry reforming of methane. Benefiting from efficient photon‐to‐phonon conversion pathway and a dynamic OL‐OV cycle, the catalyst achieves high syngas production rates and light‐to‐chemical energy efficiency without external heating ...
Chengzhi Guo   +11 more
wiley   +2 more sources

Ionentransfer während der Ionomer Kontaktelektrifizierung: Bindungsaffinität steuert Aufladung

open access: yesAngewandte Chemie, EarlyView.
Die Bindungsaffinität zwischen mobilen Ionen und fixierten Ionomergruppen bestimmt die Menge an Ladung, die während der Kontaktelektrifizierung übertragen wird. Ionomere mit einer Reihe mobiler Alkalikationen sowie mobiler Anionen zeigen eine klare Reihenfolge beim Ladungstransfer, wobei höhere Interaktionsstärke zu geringerem Ladungstransfer führt ...
John R. Hoffman   +2 more
wiley   +1 more source

Adaptive Hydrogenation of Alkynes Using CO as a Molecular Trigger to Selectively Produce Alkanes or Z‐Alkenes

open access: yesAngewandte Chemie, EarlyView.
One catalyst for two products: CO acts as a molecular trigger for adaptive alkyne hydrogenation using supported Pd nanoparticles. The catalyst reversibly switches between the formation of alkanes under H2 and Z‐alkenes under H2/CO for 37 structurally diverse alkynes.
Manisha Durai   +7 more
wiley   +2 more sources

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