Results 221 to 230 of about 206,818 (296)

Electric Double Layer Engineering Induces O‐Down Interfacial Water Reorientation for Efficient and Long‐Term Seawater Electrolysis

open access: yesAdvanced Energy Materials, EarlyView.
The additive EDTMPS inhibits hydroxides deposition by chelating with Ca2+/Mg2+. It also disrupts the hydrogen bond network of interfacial water and expands the thickness of electric double layer, promoting more free water to flip into adsorbable O‐down configuration.
Tongzhou Li   +7 more
wiley   +1 more source

Mechanistic Origin of Capacity Limitation in Sidorenkite‐Type Na3‐xFe(PO4)(CO3) Carbonophosphate Cathodes for Na‐Ion Batteries

open access: yesAdvanced Energy Materials, EarlyView.
The potential–capacity profile reveals a one‐electron limitation in sidorenkite Na3−xFe(PO4)(CO3). Structural analysis shows that Fe4+ formation induces lattice strain and suppresses electronic conductivity, blocking further Na extraction. These findings establish key design rules: preserve crystallinity, avoid Jahn–Teller–active d4 configurations, and
Samuel Franz Gatti   +7 more
wiley   +1 more source

Configurational Entropy and Compositional Effects in Fe‐Based Oxide 2D Sheets for Nitrate Electroreduction

open access: yesAdvanced Energy Materials, EarlyView.
FeCuCoMnZnOx integrates diverse heteroatomic bridge‐site environments and composition‐dependent electronic structures to promote nitrate activation and sequential hydrogenation toward ammonia, demonstrating that nitrate reduction reaction performance is governed by the combined effects of composition and local coordination rather than configurational ...
Muhammad Usman   +14 more
wiley   +1 more source

Coprecipitation‐Enabled Scalable Synthesis of High‐Energy Density Polyanion‐Integrated Disordered Rocksalt Cathodes for Lithium‐Ion Batteries

open access: yesAdvanced Energy Materials, EarlyView.
A coprecipitation‐enabled solid‐state route enables scalable synthesis of the metastable polyanion‐integrated disordered rocksalt cathode, Li1.67Mn1.5P0.17O4, without mechanochemical phase formation or post‐synthesis pulverization. Coprecipitation establishes local Mn–P–O integration in the precursor, while eutectic LiOH/LiNO3‐assisted lithiation ...
Hsi Chen   +5 more
wiley   +1 more source

Mechanochemical Defluorination of Polytetrafluoroethylene (PTFE) With Base Metals

open access: yesAngewandte Chemie, EarlyView.
Polytetrafluoroethylene (PTFE) mechanochemically reacts with safe‐to‐handle, abundant, and inexpensive base metals Zn and Al, as well as with metals like Cd and Pb, to produce sp2‐carbon and industrially important metal fluorides. The reactivity presents PTFE as a mechanochemical fluorination agent, with opportunities for closed‐loop reductive ...
Anže Zupanc   +10 more
wiley   +2 more sources

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