A Strong Lewis Acidic Diethylsilylium Catalyst for Direct Sulfonamidation of Challenging Ketones
Low‐substitution‐order silylium ions (R2HSi+) exhibit exceptional Lewis acidic activity. We report diethylsilylium‐catalyzed reductive sulfonamidation of functionalized ketones to access β‐amino esters. The in situ generated ion pair shows enhanced reactivity, with diethylsilane serving as both reductant and precatalyst. The developed protocol proceeds
Woo Hee Kim +5 more
wiley +1 more source
Mapping the Use of Information and Communication Technologies in Health Interventions for Older Adults: A Rapid Review. [PDF]
Silva AB +5 more
europepmc +1 more source
Inspired by biological ion transport, this work introduces self‐powered multifunctional sensors utilizing tailored hydrogel stacks. Optimizing ionic migration with MXenes and carbon nanotubes achieves high‐performance energy harvesting and unique logic circuit functionality.
Haoran Chen +9 more
wiley +1 more source
Identification and genetic validation of potential therapeutic targets for pulmonary hypertension through multi-omics causal inference. [PDF]
Wu C +5 more
europepmc +1 more source
Photonic‐Enabled Energy‐Efficient Transparent Neuromorphic Computing Devices: A Review
Transparent photonic neuromorphic computing devices merge optics and brain‐inspired computing to overcome von Neumann bottlenecks with ultrafast, low‐energy processing. By exploiting transparent oxides, 2D materials, phase‐change materials, and hybrid heterostructures, these platforms enable photonic synapses, memory, and logic for see‐through edge ...
Shuvaraj Ghosh +8 more
wiley +1 more source
Case Report: Malignant Interstitial Cell Tumor with Pulmonary Metastases in an Aging Naïve Fischer 344 Rat. [PDF]
Reineking W +3 more
europepmc +1 more source
High Free‐Volume Imidazole‐Based Ionomers for High‐Temperature Proton Exchange Membrane Fuel Cells
High free‐volume imidazole‐based ionomers (PF4IM‐72) enable enhanced phosphoric acid uptake and efficient proton transport, delivering peak power densities of 0.645 W cm−2 at 160 °C and 0.838 W cm−2 at 200 °C in HT‐PEMFCs. This work highlights a promising platform for next‐generation ionomers with improved high‐temperature performance and stability ...
Ge Chao +7 more
wiley +1 more source
Causal relationships between cerebrospinal fluid metabolites, immune cell traits, and head and neck cancers. [PDF]
Liu F, Gan L, Cai X, Chen Z.
europepmc +1 more source
Bias‐Tunable Two‐Terminal Organic Photodetector for Intelligent Imaging
A vertically stacked two‐terminal photodetector with a symmetric donor–acceptor–donor trilayer active exhibits reconfigurable photoresponse with bias‐tunable magnitude and polarity, together with sub‐millisecond response speed and a wide tunable output window.
Sangin Hahn +2 more
wiley +1 more source
The fundamental nature of anion storage in p‐type organic cathodes is elucidated using rigid poly(arylamine) frameworks. This study reveals a hybrid covalent‐ionic mechanism for anion‐π+ interactions, driven by synergistic orbital hybridization and electrostatic attraction.
Tiantian She +7 more
wiley +1 more source

