Results 201 to 210 of about 1,513,636 (271)

Time‐Resolved Multidimensional NMR Spectroscopy Reveals the Bifurcated Folding Pathway of a Thrombin‐Binding DNA G4–Azobenzene Derivative Complex

open access: yesAngewandte Chemie, EarlyView.
A photoswitchable ligand was used to trigger conformational changes within the thrombin binding aptamer DNA G‐Quadruplex. These reversible ligand driven rearrangements were examined by time‐resolved NMR experiments to gain insight of the dynamic folding landscape of the G‐quadruplex.
Jason Martins   +2 more
wiley   +2 more sources

To Greater Twist: A Kinetically Biased π‐Radical Cascade

open access: yesAngewandte Chemie, EarlyView.
π‐Radical cascades enable step‐economic construction of complex polycyclic aromatic frameworks. In this work, we show that a multifurcating pathway can be kinetically steered toward a single, more distorted product. This counterintuitive “falling‐upward” outcome arises from an intrinsic mechanistic bias, revealing a broader dimension of control in π ...
Yong Yang   +8 more
wiley   +2 more sources

Evaluating the Effectiveness of a Pre-Medical Pathway Program Containing Strengths-Based Innovations. [PDF]

open access: yesPerspect Med Educ
Giacomotto G   +6 more
europepmc   +1 more source

Prevalence and Correlates of Impostor Syndrome and Self-Esteem among Medical Students. [PDF]

open access: yesInt J Prev Med
Zafar M   +7 more
europepmc   +1 more source

Elucidating Liquid‐Phase Guest Transport Across MOF Single Crystals: Interplay of Adsorption, Desorption, and Intracrystalline Diffusion

open access: yesAngewandte Chemie, EarlyView.
Guest transport across metal–organic framework (MOF) single crystals disentangles transport occurring through the micropores from contributions at grain boundaries. Even guest molecules with identical kinetic diameters show drastically different transport behavior arising from the distinct modes of adsorption. Neither pore clogging nor surface collapse
Hochul Woo   +2 more
wiley   +2 more sources

Health profession students' anxiety, depression, and imposter syndrome in a rural versus urban setting. [PDF]

open access: yesBMC Med Educ
Sperling EL   +7 more
europepmc   +1 more source

NHC‐Copper(I)‐Mediated Functionalization of White Phosphorus

open access: yesAngewandte Chemie, EarlyView.
White phosphorus is functionalized by N‐heterocyclic carbene supported copper(I) complexes through redox‐neutral steps. Treatment of the resulting complexes with electrophiles releases the ligands from the metal center as asymmetrically substituted organophosphorus butterfly compounds.
Thomas M. Horsley Downie   +4 more
wiley   +1 more source

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