Results 181 to 190 of about 86,385 (292)

Mechanically Regulated Nanozymes for Remote Metabolic Reprogramming and Precise Cancer Therapy

open access: yesAngewandte Chemie, EarlyView.
Inspired by mechanoenzymes, a ferrocene‐based mechanically regulated nanozyme converts acoustic shear force into enhanced peroxidase‐like activity by decreasing electron density and alleviating steric hindrance at the Fe active sites, thereby rewiring redox homeostasis. Leveraging this remote regulatory mechanism, a multienzyme‐regulated nanoreactor is
Fangman Chen   +13 more
wiley   +2 more sources

Data‐ and Theory‐Guided Design of Dual‐Role V‐Doped RuO2 for High‐Performance Acidic Oxygen Evolution

open access: yesAngewandte Chemie, EarlyView.
A data‐ and theory‐guided paradigm, leveraging large‐scale data mining of 718 catalysts and microkinetic modeling, identifies V‐doped RuO2 as optimal for acidic OER. Vanadium doping drives electron withdrawal from Ru centers, generating Lewis acidic sites that polarize O–H bonds and accelerate deprotonation kinetics. Experimental validation achieves an
Zhongliang Liu   +10 more
wiley   +2 more sources

Electrothermal Oxidation of Ethylene Glycol Over Co3O4

open access: yesAngewandte Chemie International Edition, EarlyView.
Pressurized electrothermal oxidation of ethylene glycol enhances catalytic performance toward glycolate under mild conditions. Higher reaction rates occur at 70–90°C and 15 bar O2, and potential and O2 pressure re‐oxidize Co2+ to Co3+ at the surface.
Adarsh Koul   +9 more
wiley   +1 more source

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