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An Open-and-Shut Strategy: Preparation of Benzofused Indans by Ring-Opening of a Vinylogous Acyl Triflate and Metal-Catalyzed Asao—Yamamoto Benzannulation.

, 2010
A combination of tandem addition—fragmentation of vinylogous acyl triflates (II), (XII) towards iodobenzene derivatives and intramolecular benzannulation of o-alkynylphenyl ketones (VI) and (XIII) is successfully applied as novel strategy for the ...
David M. Jones, G. Dudley
semanticscholar   +1 more source

Synthesis and nuclear magnetic resonance spectroscopy of indane structures: indanes mono- and disubstituted in the pentagonal ring [PDF]

open access: possibleCanadian Journal of Chemistry, 1991
Indanes monosubstituted and 1,2- and 1,3-disubstituted in the pentagonal ring were synthesized, and configurations were assigned to the 1,2-disubstituted compounds by means of nuclear magnetic resonance spectroscopy. Key words: mono- and disubstituted indanes, conformation, configuration, 1H and 13C NMR, synthesis.
Adriana F. Ibanez   +4 more
openaire   +1 more source

Model Studies Toward the Synthesis of Natural Indans Utilizing a Thallium(III)-Mediated Ring-Contraction Reaction

, 2003
6-Methoxy-1-tetralone was transformed in six steps into an indan derivative related to the sesquiterpenes mutisianthol and jungianol. Key steps involve a thalium(III)-promoted ring-contraction (to assemble the indan unit)and a Wittig olefination (to ...
H. Ferraz, A. M. Aguilar, L. Silva
semanticscholar   +1 more source

Synthesis of 2-Sulfonyl Indenes and Indanes

The Journal of Organic Chemistry, 2019
In this paper, we developed facile and high-yield synthetic routes for the preparation of 2-sulfonyl indenes and indanes, including: (i) Amberlyst-15-promoted Knoevenagel reaction of β-ketosulfones and arylaldehydes in refluxing toluene; (ii) Grignard reagent (R'MgBr) or reducing reagent (NaBH4) promoted regio- and/or stereocontrolled 1,4-addition or 1,
Meng-Yang Chang   +3 more
openaire   +3 more sources

Die Reduktion des Indans mit Natrium und Alkohol in flüssigem Ammoniak

, 1958
Die Reduktion des Indans mit Natrium und Alkohol in flussigem Ammoniak wird beschrieben und die Konstitution des entstehenden 4,7-Dihydro-indans bewiesen.
E. Giovannini, H. Wegmüller
semanticscholar   +1 more source

Rearrangement of Homoallylic Alcohols with Thallium(III): Diastereoselective Synthesis of Indans Bearing a β-Hydroxy Ketone Moiety

, 2007
Several aspects of the synthesis of indans through a thallium(III)-mediated ring contraction reaction of 1,2-dihydronaphthalene derivatives bearing suitably positioned primary and secondary hydroxyl groups are disclosed.
L. Silva   +4 more
semanticscholar   +1 more source

Ring puckering splitting and structure of indan

Journal of Molecular Spectroscopy, 2015
The ground state ring puckering splitting of the cyclopentane ring of indan has been precisely determined (Delta E-01 = 22.364(1) MHz) by measuring the very weak mu(c)-type transitions with pulse jet Fourier transform microwave spectroscopy. In addition, the rotational spectra of all C-13 monosubstituted isotopologues have been assigned and measured in
Favero, Laura B.   +3 more
openaire   +4 more sources

ChemInform Abstract: Synthesis and NMR Spectroscopy of Indan Structures: Indans Mono‐ and Disubstituted in the Pentagonal Ring.

ChemInform, 1991
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
J. M. Aguirre   +4 more
openaire   +2 more sources

Novel Route to Functionalized Indans via Formal [3 + 2] Cycloadditions of 1-Benzylbenzotriazoles with Alkenes

, 1997
α-Functionalized 1-benzylbenzotriazoles (3, 4 and 12), derived from the lithiation of 1-(2,3-dimethoxybenzyl)benzotriazole 2 followed by reactions with electrophiles, or from the condensation of benzyl alcohol 11 with benzotriazole, undergo formal [3 + 2]
A. Katritzky, Guifen Zhang, L. Xie
semanticscholar   +1 more source

The Indans Formed by Dimerization of Some Aromatic Terpenoids

, 1986
Previous work upon the dimerization of carvacrol derivatives to form indans is corrected. During attempts to synthesize compound (I), the diterpenoid occurring in Callitris macleayana heartwood,' we had occasion to reflux the o-quinol acetate (2) with ...
R. Carman, N. Vandonge
semanticscholar   +1 more source

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