Results 11 to 20 of about 5,146 (108)

Enhancing NMR Signals in Liquids by Fluorine‐19 Overhauser Dynamic Nuclear Polarization (DNP) and Hyperpolarization Transfer to Carbon‐13

open access: yesAngewandte Chemie, Volume 137, Issue 50, December 8, 2025.
Fluorine nuclear spins can be hyperpolarized in solution by Overhauser dynamic nuclear polarization from a paramagnetic agent like galvinoxyl. This hyperpolarization can be transferred by nuclear magnetic resonance (NMR) to nearby 13C, leading to 13C signal enhancements up to ∼100.
Maik Reinhard   +7 more
wiley   +2 more sources

Unprecedented Selectivity for Arsenic(III) in a Dimercaptosuccinic Acid‐Based Zr‐MOF: The Role of Dangling Ligands

open access: yesAngewandte Chemie, Volume 137, Issue 48, November 24, 2025.
Highly defective DMSA‐based zirconium metal–organic framework (Zr‐DMSA‐MOF) removes arsenic from water with higher selectivity over phosphate than conventional Zr‐MOFs. X‐ray absorption spectroscopy, pair distribution function analysis, and solid‐state NMR reveal that, unlike other Zr‐based MOFs where arsenic binds to the clusters, the flexible ...
Timo M. O. Felder   +8 more
wiley   +2 more sources

Peptide‐Carbazolyl Cyanobenzene Conjugates: Enabling Biomolecule Functionalization via Photoredox and Energy Transfer Catalysis

open access: yesAngewandte Chemie, Volume 137, Issue 32, August 4, 2025.
We introduce two methods for incorporating carbazolyl cyanobenzenes onto peptides: a C‐terminus decarboxylative functionalization and a Cys‐selective SNAr reaction. Both conjugates exhibit excellent photoredox/energy‐transfer properties, enabling their use for C‐terminal alkynylation and Cys‐selective thiol‐ene reactions on peptides, as well as ...
Xing‐Yu Liu   +4 more
wiley   +2 more sources

The Versatility of Imidazole and Imidazolium Scaffolds in Sustainable Chemistry and Energy Conversion

open access: yesHelvetica Chimica Acta, EarlyView.
This review highlights the expanding applications of imidazole‐based compounds in sustainable chemistry and energy technologies. It emphasizes their roles in catalysis, solar cells, and future interdisciplinary strategies for developing advanced functional materials.
Lianghui Li   +4 more
wiley   +1 more source

Oriented Crystallization of Perovskite Film via Fluorine‐Containing Hyperbranched Polymer for Efficient and Stable Perovskite Solar Cells

open access: yesAdvanced Materials, Volume 38, Issue 2, 8 January 2026.
A fluorine‐containing hyperbranched polymer is developed to guide oriented crystallization and construct a cross‐linked hydrophobic network, enabling the formation of high‐quality perovskite films with enhanced environmental stability. The resulting devices deliver a PCE of 26.05% (0.04 cm2) and 22.43% (16.1 cm2), while maintaining 97% of their initial
Junyi Huang   +13 more
wiley   +1 more source

Systematic Evaluation of Polarizing Agents for Dynamic Nuclear Polarization Enhanced NMR

open access: yesAngewandte Chemie, Volume 137, Issue 31, July 28, 2025.
Thirty‐two polarizing agents consisting of dinitroxide and hetero biradicals are compared at magnetic fields of 9.4 T, 14.1 T, and 21.1 T, in organic and aqueous solvents. Their detailed enhancement factors, polarization build‐up times, contribution factors, and the resultant overall sensitivity gains are measured.
Ran Wei   +18 more
wiley   +2 more sources

Electron‐Selective Naphthalimide‐Based Monolayers for Tuned Energy Level Alignment in Halide Perovskite Solar Cells

open access: yesAdvanced Energy Materials, Volume 15, Issue 48, December 23, 2025.
Self‐assembled naphthalimide‐based molecular layers unlock high‐efficiency electron‐selective contacts in perovskite solar cells. Systematic tuning of substituents and linker lengths reveals key structure–function relationships, achieving up to 20.6% PCE without charge‐selective metal oxide layers.
Parnian Ferdowsi   +10 more
wiley   +1 more source

1,2‐Bis‐Triazenylarenes Enable Vicinal Sandmeyer‐Type Reactions

open access: yesAngewandte Chemie, Volume 137, Issue 21, May 19, 2025.
1,2‐Bis‐triazenylarenes enable vicinal disubstitution reactions. The reactions can be performed in one step or in a sequential fashion, and they allow introducing a range of different nucleophiles including fluoride, chloride, bromide, iodide, azide, hydroxide, methoxide, and acetamide.
Christeena Mathew   +5 more
wiley   +2 more sources

Testing Protocols for Obtaining Reliable Pair Distribution Functions from Laboratory X‐Ray Sources Using PDFgetX3

open access: yesChemistry–Methods, Volume 5, Issue 9, September 2025.
This work explores data acquisition and reduction protocols for atomic pair distribution scheme that enhances high‐angle data collection, and the effects of instrumental parameters on resulting pair distribution functions are examined. A correction for sample absorption in PDFgetX3 is introduced. Herein, data acquisition protocols are explored and data
Till Schertenleib   +5 more
wiley   +1 more source

Stability and performance of two GSBR operated in alternating anoxic/aerobic or anaerobic/aerobic conditions for nutrient removal [PDF]

open access: yes, 2012
Two granular sludge sequencing batch reactors (GSBR) with alternating anoxic/aerobic (R1) and anaerobic/aerobic (R2) conditions were operated with a 4-carbon-source synthetic influent. The physical properties of the granular sludge were very good (SVI≈20
Bessiere, Yolaine   +5 more
core   +3 more sources

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