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Intercalation Chemistry of Ionic Liquids
ECS Transactions, 2013The use of ionic liquids as electrolytes for the intercalation of TiS2 by Li+ and Mg++ has been studied using a short chain and long chain substituted imidazolium based ionic liquid: 1,2-dimethyl-3-n-propylimidazolium and 1,2-dimethyl-3-n-ocylimidazolium, both paired with the bis(trifluoromethanesulfonyl)imide anion.
Thomas Edward Sutto, Teresa Tua Duncan
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Biochimica et Biophysica Acta (BBA) - Nucleic Acids and Protein Synthesis, 1976
The synthesis, as well as the rationale for synthesis of diacridines, double intercalators, as potential inhibitors of nucleic acid synthesis is presented. The syntheses of (9-acridyl)-putrescine and -spermine, and bis(-9-acridyl)-putrescine, -spermidine, -spermine diamines and of bis(6-chloro-2-methoxy-9-acridyl)-putrescine and -spermine diamines, all
E S, Canellakis +3 more
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The synthesis, as well as the rationale for synthesis of diacridines, double intercalators, as potential inhibitors of nucleic acid synthesis is presented. The syntheses of (9-acridyl)-putrescine and -spermine, and bis(-9-acridyl)-putrescine, -spermidine, -spermine diamines and of bis(6-chloro-2-methoxy-9-acridyl)-putrescine and -spermine diamines, all
E S, Canellakis +3 more
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Graphite intercalation chemistry with large fluoroanions
Journal of Fluorine Chemistry, 2004Abstract The syntheses and structures of graphite intercalations compounds (GIC's) containing perfluoroalkylimide, perfluoroalkylsulfonate, or perfluoroalkylborate ester anions are described. Synthetic methods include both chemical oxidation, typically performed using K 2 MnF 6 in concentrated hydrofluoric or hydrofluoric/nitric acids, and ...
Wei Yan +4 more
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Phase transitions in intercalation chemistry
Phase Transitions, 1991Abstract The intercalation of cations in a given host structure, often a low-dimensional solid, is the result of a reversible ion-electron transfer reaction which is classically represented by the scheme: Most of the features related to the positions taken by the A+ cations are rather well understood.
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Physical Chemistry of Intercalated System
2014The driving force of development of intercalation chemistry is significant improvement of properties of fabricated nanocomposites and design of materials with new properties. Forming hybrid structures define important functional characteristics: improved mechanical strength (increase in modulus), enhanced stiffness, heat resistance (decrease in thermal
Anatolii D. Pomogailo +1 more
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Intercalation chemistry of zirconium 4-sulfophenylphosphonate
Journal of Solid State Chemistry, 2013Abstract Zirconium 4-sulfophenylphosphonate is a layered material which can be employed as a host for the intercalation reactions with basic molecules. A wide range of organic compounds were chosen to represent intercalation ability of zirconium 4-sulfophenylphosphonate.
Jan Svoboda +4 more
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Intercalation chemistry and chemical bonding
Journal of Physics and Chemistry of Solids, 1998Abstract In contrast to amphoteric graphite, the layer-type oxides or chalcogenides generally play the role of acceptors in chemical or electrochemical intercalation reactions. Due to the more ionic character of the MO bonds, the structural evolution of the oxides may usually be explained on hand of electrostatic considerations, or in terms of ...
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Intercalation chemistry and energy storage
Journal of Solid State Chemistry, 1979Abstract The reaction between lithium and titanium disulfide is used to show the relationship between intercalation chemistry and electrochemical energy storage. The maintenance of crystalline structure with only a 10% lattice expansion perpendicular to the sulfide sheets allows high rates of reaction with lithium and complete reversibility of the ...
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Understanding intercalation chemistry for sustainable aqueous zinc–manganese dioxide batteries
Nature Sustainability, 2022Yifei Yuan +13 more
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