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Interfacial Polymerization at the Alkane/Ionic Liquid Interface [PDF]

open access: yesAngewandte Chemie - International Edition, 2021
AbstractPolymerization at the liquid–liquid interface has attracted much attention for synthesizing ultrathin polymer films for molecular sieving. However, it remains a major challenge to conduct this process outside the alkane–water interface since it not only suffers water‐caused side reactions but also is limited to water‐soluble monomers.
Zhi-Kang Xu   +2 more
exaly   +6 more sources

Microscale Interfacial Polymerization on a Chip. [PDF]

open access: yesAngew Chem Int Ed Engl, 2021
AbstractForming hydrogels with precise geometries is challenging and mostly done using photopolymerization, which involves toxic chemicals, rinsing steps, solvents, and bulky optical equipment. Here, we introduce a new method for in situ formation of hydrogels with a well‐defined geometry in a sealed microfluidic chip by interfacial polymerization. The
Rocca M   +4 more
europepmc   +7 more sources

Electrostatic-modulated interfacial polymerization toward ultra-permselective nanofiltration membranes [PDF]

open access: yesiScience, 2021
Summary: Interfacial polymerization (IP) is a platform technology for ultrathin membranes. However, most efforts in regulating the IP process have been focused on short-range H-bond interaction, often leading to low-permselective membranes.
Xinda You   +10 more
doaj   +2 more sources

Alginate Hydrogel Assisted Controllable Interfacial Polymerization for High-Performance Nanofiltration Membranes [PDF]

open access: yesMembranes, 2021
The deepening crisis of freshwater resources has been driving the further development of new types of membrane-based desalination technologies represented by nanofiltration membranes.
Zhao-Yu Ma, Yu-Ren Xue, Zhi-Kang Xu
doaj   +2 more sources

Vacuum-Assisted Interfacial Polymerization Technique for Enhanced Pervaporation Separation Performance of Thin-Film Composite Membranes [PDF]

open access: yesMembranes, 2022
In this work, thin-film composite polyamide membranes were fabricated using triethylenetetramine (TETA) and trimesoyl chloride (TMC) following the vacuum-assisted interfacial polymerization (VAIP) method for the pervaporation (PV) dehydration of aqueous ...
Marwin R. Gallardo   +5 more
doaj   +2 more sources

Microencapsulation of Photochromic Solution with Polyurea by Interfacial Polymerization. [PDF]

open access: yesPolymers (Basel), 2021
Photochromic materials are interesting materials because of their color-changing property under UV light and visible light irradiation. However, they are vulnerable to many factors, such as pH oxygen, ion, solvent, etc. because of the unsaturated bonds existing on the photochromic molecular. Microencapsulation of the photochromic materials can separate
Zhang Y, Zhang X, Yan Y, Chen Z.
europepmc   +4 more sources

Thermal-intensified interfacial polymerization enables ultra-selective reverse osmosis membrane for toxic micropollutant removal [PDF]

open access: yesNature Communications
Polyamide reverse osmosis (RO) membranes are widely used in seawater desalination and wastewater reuse, yet often fail to remove small toxic micropollutants.
Shenghua Zhou   +4 more
doaj   +2 more sources

When self-assembly meets interfacial polymerization. [PDF]

open access: yesSci Adv, 2023
Interfacial polymerization (IP) and self-assembly are two thermodynamically different processes involving an interface in their systems. When the two systems are incorporated, the interface will exhibit extraordinary characteristics and generate structural and morphological transformation.
Shen Q   +8 more
europepmc   +3 more sources

Anhydrous interfacial polymerization of sub-1 Å sieving polyamide membrane [PDF]

open access: yesNature Communications, 2023
Highly permeable polyamide (PA) membrane capable of precise ionic sieving can be utilized for many energy-efficient chemical separations. To fulfill this target, it is crucial to innovate membrane-forming process to induce a narrow pore-size distribution.
Guangjin Zhao   +4 more
doaj   +2 more sources

A Multi-Scale Approach to Microencapsulation by Interfacial Polymerization. [PDF]

open access: yesPolymers (Basel), 2021
This work applies a multi-scale approach to the microencapsulation by interfacial polymerization. Such microencapsulation is used to produce fertilizers, pesticides and drugs. In this study, variations at three different scales (molecular, microscopic and macroscopic) of product design (i.e., product variables, process variables and properties) are ...
Ricardo F   +3 more
europepmc   +4 more sources

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