In a proof‐of‐concept study, it was for the first time shown that planar chiral trans‐cycloalk‐2‐enones, such as 2, can be formed enantioselectively from their cis‐isomers by triplet energy transfer from a chiral catalyst. Computational studies performed with cyclohept‐2‐enone and enone 1 provided invaluable insights into the mode of action of the ...
Max Stierle+10 more
wiley +2 more sources
“Who's breaking the law … not us, them!”: Inside immigration detention in Portugal
Abstract In this paper, we examine immigration detention in Portugal, a system whose daily operations and inherent violence are overlooked in both public and academic discourses. Even within community psychology, discussions on immigration detention have largely remained on the fringes of scholarly debates. Guided by a justice‐centered ecological lens,
Francesca Esposito+3 more
wiley +1 more source
Site‐Selective Carbonylation of Azetidines via Copper‐Catalyzed Difluorocarbene Insertion
We disclose a site‐selective Cu‐catalyzed carbonylation of azetidines promoted by difluorocarbene insertion at low temperature, enabling access to a variety of functionalized γ‐lactams and a therapeutic agent for diabetes (40 examples). This skeletal expansion strategy provides a distinct disconnection approach to synthesize medicinally relevant five ...
Fang Zhou, Tong‐De Tan, Ming Joo Koh
wiley +2 more sources
A novel IoT-device management platform for on-the-fly generation of user interface via manifest-file addressing heterogeneity. [PDF]
Gupta N+3 more
europepmc +1 more source
A Performance Analysis of Security Protocols for Distributed Measurement Systems Based on Internet of Things with Constrained Hardware and Open Source Infrastructures. [PDF]
Gentile AF+4 more
europepmc +1 more source
Intelligent two-phase dual authentication framework for Internet of Medical Things. [PDF]
Asif M+6 more
europepmc +1 more source
Rapid implementation of open-access pandemic education for global frontline healthcare workers. [PDF]
Christianson J+4 more
europepmc +1 more source
Computational protocol for analyzing whole-genome sequencing data from Staphylococcus aureus clinical isolates. [PDF]
Sánchez-Osuna M+3 more
europepmc +1 more source
Transmission Control Protocol (TCP)-Based Delay Tolerant Networking for Space-Vehicle Communications in Cislunar Domain: An Experimental Approach. [PDF]
Wang D, Wang R.
europepmc +1 more source
Sustainable Pathways for the Synthesis of Calcium Sulfate Hemihydrate
Calcium sulfate hemihydrate (bassanite) plays a key role in construction as a hydraulic binder. Due to its instability in water, industrial production primarily relies on thermal dehydration of gypsum. This review examines alternative, potentially more sustainable methods for the synthesis of bassanite, including gypsum conversion at lower temperatures
Selina Reigl+5 more
wiley +1 more source