Results 101 to 110 of about 9,652 (250)

Spin‐Orbit Coupling‐Modulated Ultrafast Spin‐Flip of Singlet/Triplet Self‐Trapped Exciton Near‐Infrared‐II Emission in Highly Distorted Manganese Iodide Dimer for Optical Multiplexing

open access: yesAggregate
Self‐trapped excitons (STEs) are generating significant interest due to their broadband emission and self‐absorption‐free advantages. However, achieving high‐efficiency singlet/triplet STE near‐infrared (NIR) emissive tuning remains challenging issues ...
Fangxue Chen   +9 more
doaj   +1 more source

Photo‐Switchable FRET‐Enabled Flexible Luminescent Films for Multilevel Optical Security

open access: yesCarbon Energy, EarlyView.
A light‐gated FRET composite integrates a Tb‐Phen donor and a spiropyran acceptor in a polyurethane matrix. Under 365 nm light, spiropyran is transformed into merocyanine, creating spectral overlap with Tb3+ emission and activating energy transfer. Visible light reverses the switch, restoring green emission and enabling reversible multilevel optical ...
Zihui Liang   +10 more
wiley   +1 more source

Benzo[c][1,2,5]Thiadiazole Linkers Enhance the Effectiveness of Cavity‐Containing Supramolecular Photocatalysts

open access: yesChemistry – A European Journal, EarlyView.
Seven novel supramolecular photosensitizers based on benzo[c][1,2,5]thiadiazole (BTZ) tethered to calix[4]arene (C[4]) scaffolds are reported with facile, scalable, and selective syntheses. Their abilities to produce singlet oxygen have been tested through the photo‐oxidation of α‐terpinene.
Leonardo Amicosante   +6 more
wiley   +1 more source

β‐Ketonitrile‐Modified Prodan Derivatives as Large‐Stokes‐Shift Solvatochromic Fluorophores With Enhanced Brightness and Ratiometric Thermometric Response

open access: yesChemistry – A European Journal, EarlyView.
We report a systematic study of β‐ketonitrile–modified Prodan‐type solvatochromic fluorophores. The β‐ketonitrile substitution induces marked bathochromic shifts in absorption and emission and significantly enhances fluorescence quantum yields in nonpolar solvents.
Hiroaki Asakawa   +3 more
wiley   +1 more source

Exploring the Boundaries of Aromaticity in Complex Structures and Excited States Through Computational Analysis

open access: yesChemistry – A European Journal, EarlyView.
Understanding aromaticity has evolved from benzene‐centric concepts to a broad multidimensional framework spanning organic, inorganic, and excited‐state systems. This review highlights ambiguities between magnetic, electronic, geometric, and energetic descriptors, emphasizing the need for unified, multi‐criteria approaches.
Sílvia Escayola   +2 more
wiley   +1 more source

Turning Bonding Into Function: The Emerging Role of the Bioactive Selenium─Metal Motif in Toxicology and Medicinal Chemistry

open access: yesChemistry – A European Journal, EarlyView.
Balancing Act: Se─M bond serving as the fulcrum of the balance scale to compare the different weight of toxicity and therapeutic effects in biological environment. ABSTRACT The synthesis and characterization of organo‐selenium compounds have attracted considerable interest for decades, driven by the search for efficient catalysts and bioinspired ...
Matteo Filippi   +6 more
wiley   +1 more source

Decoupling Triplet Population from Intersystem Crossing in TADF Materials. [PDF]

open access: yesJ Am Chem Soc
Holdsworth EM   +10 more
europepmc   +1 more source

Photostability of Cyanine Dyes and Its Correlation to Their Photothermal and Photodynamic Effects

open access: yesChemistry – A European Journal, EarlyView.
Photostability (PS) of dyes is a crucial parameter for performance in biological applications, yet often underrated. Here PS of several cyanines is investigated. The method is carefully evaluated and designed as a general and easy tool to compare PS of NIR dyes.
Clara Schäfer, Bo W. Laursen
wiley   +1 more source

Photochemical afterglow of single organic molecules with wide‐range tunable lifetime

open access: yesPhotoMat, EarlyView., 2023
“All‐in‐one” strategy was used to achieve photochemical afterglow in single organic molecule, with second‐to‐hour range tunable lifetime by tailoring the electron‐withdrawing ability of substituents. Abstract Background Photochemical afterglow that relies on slow release of photons from the chemical energy stored by light pre‐irradiation has emerged as
Yuetian Pei   +6 more
wiley   +1 more source

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