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Ultrafast intersystem crossing in a transition metal complex
The Thirteenth International Conference on Ultrafast Phenomena, 2002Intersystem crossing is an important aspect of virtually all photophysical and photochemical processes involving transition metals. One of the most extensively studied transition metal ions is chromium(III)[1,2]. A diagram of this ion’s electronic structure, depicting d-electrons under octahedral symmetry, is illustrated in Figure 1.
Eric A. Juban, James K. McCusker
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Intersystem Crossing in Complex Molecules
1980The general question of singlet-triplet intersystem crossing is addressed in the context of large organic molecules, i.e., “complex” molecules capable of self-relaxation in the absence of collisions. Examples of spectral properties of such molecules in the vapor phase are discussed, relying on extensive Russian literature in this area.
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Influence of Solvent on Carbene Intersystem Crossing Rates
Journal of the American Chemical Society, 2008The influence of coordinating solvents on singlet-to-triplet carbene intersystem crossing (ISC) rates has been studied with diphenylcarbene (DPC) and para-biphenyltrifluoromethylcarbene (BpCCF 3) by using ultrafast time-resolved spectroscopy. DPC has a triplet ground state in all of the solvents considered, and the concentration of singlet carbene at ...
Jin, Wang +3 more
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Intersystem Crossing and Multiple Tunnelling
physica status solidi (b), 1969AbstractThe problem of non‐adiabatic tunnelling in the system of two coupled parabolic terms interacting with the environment has been solved. The model is applied to intersystem crossing in the simple centre of luminescence. The role of multiple passage through the region of term interaction has been cleared up.
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Intersystem crossing in hexahelicene
Journal of the American Chemical Society, 1979S. S. Kim, S. I. Weissman
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Intersystem Crossing in Pyrene
The Journal of Chemical Physics, 1967B. Stevens, M. F. Thomaz, J. Jones
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Experimentally Observed Reverse Intersystem Crossing‐Boosted Lasing
Angewandte Chemie - International Edition, 2020Qian Peng +2 more
exaly

