How state transitions balance photosynthetic electron transport in plants – a quantitative study
Summary In plants, the process of state transition regulates the allocation of sunlight energy between Photosystem II (PSII) and PSI. However, the implications of state transitions for harmonizing electron transport rates between photosystems, and a full quantitative picture of this process, remain underexplored.
Haniyeh Koochak +4 more
wiley +1 more source
Efficient intersystem crossing and tunable ultralong organic room-temperature phosphorescence via doping polyvinylpyrrolidone with polyaromatic hydrocarbons. [PDF]
Yang G +7 more
europepmc +1 more source
Ultrafast Dynamics of Organic Exciton–Polaritons
This work reveals the conditions required to capture the coherent dynamics of organic exciton–polaritons. The ultrafast relaxation of these collective hybrid states is uniquely observed only when they sit beyond the tail of the molecular absorption. In this condition, they do not enter into equilibrium with intracavity dark states, raising questions ...
Soham Mukherjee +3 more
wiley +1 more source
Photochemical N‐dealkylation of Tertiary Amines Coupled With Photocharging of Poly(Heptazine Imides)
Protonated poly(heptazine imide) (H‐PHI) functions as an energy reservoir, thereby facilitating the endothermic dealkylation of triethylamine through a proton‐coupled two‐electron transfer (PC2ET) process. The extent of photocharging is quantitatively described by a molecular‐level descriptor, Ne:Nhept, providing a direct correlation between stored ...
Jingru Zhuang +6 more
wiley +2 more sources
Efficient harvesting of triplet excitons via multiple fast TTA up-conversion and high-lying reverse intersystem crossing channels for efficient blue fluorescent organic light-emitting diodes. [PDF]
Qin J +7 more
europepmc +1 more source
When light is applied to the negatively charged nitrogen‐vacancy (NV−$\mathrm{{NV}^{-}}$) in diamond, an applied magnetic field populates the 1E$\mathrm{^1E}$ singlet state. Wavelength tuned laser excitation probes the 1E$\mathrm{^1E}$ ionization threshold via changes in the NV0$\mathrm{{NV}^{0}}$ photoluminescence (PL) ratio which is the ratio between
Kristine V. Ung +3 more
wiley +1 more source
The Diarylprolinol Silyl Ethers: After 20 Years Still Opening New Doors in Asymmetric Catalysis
Catalysis Rules! The year 2025 marks the 20th anniversary of diarylprolinol silyl ethers in asymmetric organocatalysis. During the first decade after their discovery, these catalysts have been established as one of the most versatile tools in aminocatalysis. Although now considered mature, recent years have witnessed renewed innovation.
Enrico Marcantonio +2 more
wiley +2 more sources
Ultrafast photophysics of para-substituted 2,5-bis(arylethynyl) rhodacyclopentadienes: thermally activated intersystem crossing. [PDF]
Guo Z +11 more
europepmc +1 more source
We report the synthesis bis(arylethynyl)naphtho‐ and anthraquinones via Rh(I)‐catalyzed [2 + 2 + 2] cycloaddition reactions. The substrate scope of both quinones and linked bis‐diynes was explored. Microwave irradiation remarkably enhanced yields.
Luana A. Machado +16 more
wiley +1 more source
Nonplanar structure accelerates reverse intersystem crossing of TADF emitters: nearly 40% EQE and relieved efficiency roll off. [PDF]
Liu H +6 more
europepmc +1 more source

