Results 61 to 70 of about 28,761 (191)
Time-resolved gas-phase kinetic and quantum chemical studies of the reaction of silylene with oxygen [PDF]
, 2005 Time-resolved kinetic studies of the reaction of silylene, SiH2, generated by laser flash photolysis of phenylsilane, have been carried out to obtain rate constants for its bimolecular reaction with O-2. The reaction was studied in the gas phase over the
Adamovic, I. +7 more
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Frontiers in Chemistry, 2022 Optically excited triplet states of organic molecules serve as an energy pool for the subsequent processes, either photon energy downhill, such as room temperature phosphorescence, or photon energy uphill process—the triplet–triplet annihilation ...
Aleksey Vasilev +6 more
doaj +1 more source
Magnetocatalytic Adiabatic Spin Torque Orbital Transformations for Novel Chemical and Catalytic Reaction Dynamics: The Little Effect [PDF]
, 2006 In this manuscript the theory and phenomena associated with the Little Effect are introduced as the spin induced orbital dynamics of confined fermions under strong magnetic and thermal environments.
Little, Reginald B.
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Inverting Singlet and Triplet Excited States using Strong Light-Matter Coupling
, 2019 In organic microcavities, hybrid light-matter states can form with energies that differ from the bare molecular excitation energies by nearly 1 eV. A timely question, given recent advances in the development of thermally activated delayed fluorescence ...
Eizner, Elad +3 more
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Mechanism of Ultrafast Intersystem Crossing in 2‐Nitronaphthalene [PDF]
Chemistry – A European Journal, 2018 AbstractNitronaphthalene derivatives efficiently populate their electronically excited triplet states upon photoexcitation through ultrafast intersystem crossing (ISC). Despite having been studied extensively by time‐resolved spectroscopy, the reasons behind their ultrafast ISC remain unknown.
J. Patrick Zobel +2 more
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Spin Photochemistry: Electron Spin Multiplicity as a Tool for Reactivity and Selectivity Control
CHIMIA, 2021 Spin chemistry involving small organic molecules without heavy atoms is highly sensitive to spin-orbit-coupling (SOC) modulating biradical conformation as well as hyperfine coupling (HFC) modulating magnetic isotope interactions. Several easily available
Axel G. Griesbeck, Seyma Bozkus
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, 2014 Citation: 'intersystem crossing' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.I03123 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
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Intersystem Crossings Drive Atmospheric Gas-Phase Dimer Formation [PDF]
The Journal of Physical Chemistry A, 2019 High molecular weight "ROOR'" dimers, likely formed in the gas phase through self- and cross-reactions of complex peroxy radicals (RO2), have been suggested to play a key role in forming ultrafine aerosol particles in the atmosphere. However, the molecular-level reaction mechanism producing these dimers remains unknown.
Rashid R. Valiev +4 more
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Understanding H-aggregates crystallization induced emissive behavior: insights from theory
Scientific Reports, 2023 We conducted a theoretical investigation into how the molecular stacking effect impacts the photophysical properties in solid phases. Our findings indicated that in the aggregated state, the out-of-plane distorted vibration and imidazole ring stretching ...
Huixue Li +4 more
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Exciton-polaron complexes in pulsed electrically-detected magnetic resonance
, 2015 Several microscopic pathways have been proposed to explain the large magnetic effects observed in organic semiconductors, but identifying and characterising which microscopic process actually influences the overall magnetic field response is challenging.
Baker, W. J. +2 more
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