Results 191 to 200 of about 147,809 (300)

Atomic Precision CoCu Heterodimers with Pseudo‐D3h Symmetry Enable Tandem Nitrate Reduction

Advanced Science, EarlyView.
The Co─Cu heterodimer anchored on nitrogen‐doped graphene oxide substrate facilitates electrochemical nitrate reduction in alkaline medium. Co site promotes water dissociation to supply a proton, while Cu sites enhance nitrate adsorption and activation.
Akash Prabhu Sundar Rajan, Jayaraman Theerthagiri, Piyapa Junmon, Wanwisa Limphirat, Nuttapon Yodsin, Myong Yong Choi   +5 more
wiley   +1 more source

The role of an intramolecular hydrogen bond in the redox properties of carboxylic acid naphthoquinones. [PDF]

Chem Sci
Guerra WD, Odella E, Cui K, Secor M, Dominguez RE, Gonzalez EJ, Moore TA, Hammes-Schiffer S, Moore AL.   +8 more
europepmc   +1 more source

Conformation‐Modulated Lignin for Durable and High‐Output Cellulosic Triboelectric Materials Toward Self‐Powered Sensing

Advanced Science, EarlyView.
Conformation‐engineered alkali lignin with flexible aliphatic side chains is integrated into cellulose to suppress tribo‐induced fiber fibrillation and interfacial wear. Dynamic chain adaptability enhances frictional energy dissipation and dielectric polarization, enabling durable, high‐output triboelectric sensing with excellent recyclability and ...
Lujie Wang, Jian Du, Yilin Wang, Tianshuang Bao, Chao Li, Yehan Tao, Jinwen Hu, Chenglong Fu, Dong Lv, Weiwei Zhao, Zhanhui Yuan, Haisong Wang   +11 more
wiley   +1 more source

Revisiting the Case of an Intramolecular Hydrogen Bond Network Forming Four- and Five-Membered Rings in d-Glucose. [PDF]

ACS Omega, 2018
Martins FA, Freitas MP.
europepmc   +1 more source

Dual Effect of Steric Hindrance in Non‐Aqueous Amine Absorbents: Navigating the Trade‐Off Between Kinetics and Thermodynamics for Efficient CO2 Capture

Advanced Science, EarlyView.
This study elucidates how steric hindrance in amines creates a dual effect in CO2 capture: it thermodynamically favors the reaction by shifting the pathway from carbamate to alkyl carbonate formation, increasing capacity and lowering regeneration heat, while simultaneously slightly slowing the kinetics.
Xiaoyi Gao, Bin Xu, Xi Tang, Muyi Li, Cong Luo, Fan Wu, Xiaoshan Li, Liqi Zhang, Wen Chen   +8 more
wiley   +1 more source

A Noncovalent Click‐to‐Release Strategy to Control Bond Cleavage and Prodrug Activation

Angewandte Chemie, EarlyView.
Extending the click‐to‐release concept beyond covalent ligation, we introduce a noncovalent click‐to‐release strategy based on cucurbituril‐adamantane (CB‐Ad) association. A supramolecular preassembly encapsulating a self‐immolative guest (SIG) is rationally designed to prevent premature release, while adding a high‐affinity Ad guest initiates the CB ...
Xuancheng Fu, Bowen Xu, Suman Maity, Michelle Wu, Luke G. Westbrook, James H. Henderson, Yaoying Wu, Katie A. Edwards, Atanu Acharya, Xiaoran Hu   +9 more
wiley   +2 more sources

Beyond Silicon: Toward Sustainable, NIR‐II, and Conformable Organic Photodiodes

Advanced Energy Materials, EarlyView.
In this perspective, a strategic shift in organic photodetector (OPD) research is proposed: instead of the incremental advances in silicon's stronghold arena, the most impactful future for OPDs lies in addressing silicon's intrinsic limitations, i.e., detection in the longer wavelength range above silicon's coverage (>1100 nm, termed as near infrared ...
Hrisheekesh Thachoth Chandran, Jiaming Huang, Hao Xia, Rakesh Rajendran Nair, Shen Xing, Gang Li, Karl Leo, Johannes Benduhn   +7 more
wiley   +1 more source

Tuning Circular Dichroism and Circularly Polarised Luminescence in Single Crystals of a Perylene Diimide Macrocycle

Angewandte Chemie, EarlyView.
The circular dichroism (CD) and circularly polarised (CPL) of a bis‐perylene diimide macrocycle are measured in single crystals. These chiroptical properties are tuned by the macrocycle's π–π stacking interactions in the solid‐state. Abstract Chiral materials that manipulate circularly polarised light have burgeoning applications across optoelectronics,
Denis Hartmann, Samuel E. Penty, Artemijs Krimovs, Robert Pal, Tiberiu‐M. Gianga, Giuliano Siligardi, Timothy A. Barendt   +6 more
wiley   +2 more sources

Corrigenda - Intramolecular Hydrogen Bonding in Mononitronaphthylamines [PDF]

Australian Journal of Chemistry, 1960
A Bryson, RL Werner
openaire   +1 more source

Breaking Down Lignin: A Macromolecule's Path to the Nanoscale

Advanced Energy and Sustainability Research, EarlyView.
This section highlights lignin's critical role as a sustainable, multifunctional precursor for nanomaterial design. Its unique structure and abundance enable the creation of lignin‐based, lignin‐derived, and hybrid nanomaterials with tunable properties. Emphasis is placed on lignin's potential to drive innovation in nanotechnology, offering ecofriendly
Jelena Papan Djaniš, Jan Hočevar, Griša Grigorij Prinčič, Jernej Iskra   +3 more
wiley   +1 more source