Results 31 to 40 of about 71,662 (334)

Transition-metal free C–N bond formation from alkyl iodides and diazonium salts via halogen-atom transfer

open access: yesNature Communications, 2022
The pursuit of efficient C–N bond formation is a prime focus of synthetic organic chemistry. Here, the authors documented a base promoted amination between alkyl iodides and diazonium salts via halogen-atom transfer (XAT) process.
Jing Zhang   +11 more
doaj   +1 more source

Catch and release’ cascades: a resin-mediated three-component cascade approach to small molecules [PDF]

open access: yes, 2006
The application of a ‘catch and release’ approach to palladium-catalysed multi-component cascade reactions leads to diverse libraries of pharmacologically interesting small molecules in high yield and with excellent ...
Andrew Cook   +23 more
core   +1 more source

4-Acetylpyridinium iodide [PDF]

open access: yesActa Crystallographica Section E Structure Reports Online, 2010
In the title compound, C(7)H(8)NO(+)·I(-), N-H⋯I hydrogen bonding and π-π stacking inter-actions [centroid-centroid distance = 5.578 (4) Å] stabilize the structure.
Jie Xu, Xue-qun Fu
openaire   +3 more sources

Fungicidal and bactericidal activity of alkyl-substituting polyetherguanidines

open access: yesБіологічні студії, 2020
Background. Polyhexamethylene guanidines are widely used as biocides and disinfectants due to the wide range of their antimicrobial activity against Gram-positive and Gram-negative bacteria, viruses, fungi, and molds.
M. Ya. Vortman   +5 more
doaj   +1 more source

Visible-light promoted atom transfer radical addition-elimination (ATRE) reaction for the synthesis of fluoroalkylated alkenes using DMA as electron-donor [PDF]

open access: yes, 2020
Here, we describe a mild, catalyst-free and operationally-simple strategy for the direct fluoroalkylation of olefins driven by the photochemical activity of an electron donor-acceptor (EDA) complex between DMA and fluoroalkyl iodides.
Gu, Jiwei   +5 more
core   +2 more sources

2-Aminoethanaminium iodide [PDF]

open access: yesActa Crystallographica Section E Structure Reports Online, 2012
The title salt, [NH3CH2CH2NH2]+·I−, has an array structure based on strong intermolecular N—H...N hydrogen bonding formed between the ammonium and amine groups of adjacent cations. This interaction gives a helical chain of cations that runs parallel to the b axis.
Kennedy, Alan, Okoth, Maurice O.
openaire   +4 more sources

Nickel-catalyzed carbonylative synthesis of dihydrobenzofurans

open access: yesCatalysis Communications, 2021
A nickel-catalyzed carbonylative synthesis of dihydrobenzofurans has been developed. With Mo(CO)6 as the CO source and manganese metal as the reductant, alkyl halides were reacted with aryl iodides to give the desired products in moderate to good yields.
Hui-Qing Geng, Wei Wang, Xiao-Feng Wu
doaj   +1 more source

Synthesis of chiral cyclohexanes and carbasugars by 6-exo-dig radical cyclisation reactions

open access: yesBeilstein Journal of Organic Chemistry, 2008
Treatment of 5-(tert-butyldimethylsilyl)-2,3-O-isopropylidene-D-ribose with lithium acetylides gave mixtures of syn- and anti-alkynols 2a–2c which were separated following protection as methoxymethyl ethers.
Rajeev K. Shrivastava   +4 more
doaj   +1 more source

Synthesis of novel room temperature chiral ionic liquids. application as reaction media for the heck arylation of aza-endocyclic acrylates. [PDF]

open access: yes, 2010
New achiral and chiral RTILs were prepared using novel and/or optimized synthetic routes. These new series of imidazolinium, imidazolium, pyridinium and nicotine-derived ionic liquids were fully characterized including differential scanning calorimetry ...
Correia, Carlos R. D.   +4 more
core   +4 more sources

Synthesis of substituted Z-styrenes by Hiyama-type coupling of oxasilacycloalkenes: application to the synthesis of a 1-benzoxocane

open access: yesBeilstein Journal of Organic Chemistry, 2017
Several Hiyama cross-coupling reactions of oxasilacycloalkenes and aryl iodides are described that produce trisubstituted Z-styrenes in moderate to excellent yields.
James R. Vyvyan   +5 more
doaj   +1 more source

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