Results 81 to 90 of about 163,500 (335)

Radical Fluoroalkylation Reactions [PDF]

, 2018
Recent protocols and reactions for catalytic radical perfluoroalkylations will be described. The production of perfluoroalkyl radicals (RF = CnF2n+1, n ≥ 2), which effect both addition and substitution reactions on organic substrates, can be realized ...
Barata Vallejo, Sebastian, Cooke, María Victoria, Postigo, A.   +2 more
core   +1 more source

Exon 7 splicing of ERα predicts poor prognosis and increases phenotypic heterogeneity in luminal a subtype breast cancer

FEBS Open Bio, EarlyView.
ERα splice variant ERα∆7 lacks the C‐terminus, and its expression may change phenotypes of breast cancers. Our results showed that ERα∆7 is found in the luminal A subtype, and elevated ERα∆7 levels are linked to improved cell survival with lower proliferation and migration.
Long Wai Tsui, Taobo Hu, Thomson Christian Husein, Wai Hei Shek, Bingrong Chen, Depeng Wang, Shu Wang, Weichuan Yu, Xiaodan Fan, Mengping Long, Toyotaka Ishibashi   +10 more
wiley   +1 more source

Low-Valent Tungsten Catalyzed Carbonylative Synthesis of Benzoates from Aryl Iodides and Alcohols

Molecules
Non-noble metals catalyzed carbonylative reactions serve as straightforward and sustainable methods for the synthesis of functionalized carbonyl-containing compounds.
Feihua Ye, Lin Lu, Zhaoyang Huang, Yunwei Huang, Lixuan Huang, Chunsheng Li, Xiang Li   +6 more
doaj   +1 more source

Recent developments in the Suzuki-Miyaura reaction: 2010-2014 [PDF]

, 2015
The Suzuki-Miyaura reaction (SMR), involving the coupling of an organoboron reagent and an organic halide or pseudo-halide in the presence of a palladium or nickel catalyst and a base, has arguably become one of most utilized tools for the construction ...
Maluenda, Irene, Navarro, Oscar
core   +2 more sources

Electrical Conductivities of Conductors, Semiconductors, and Their Mixtures at Elevated Temperatures

Advanced Engineering Materials, EarlyView.
This article presents a comprehensive review of temperature‐dependent electrical conductivity data for multiple material classes at elevated temperatures, highlighting a persistent conductivity gap between metals and semiconductors in the range of 102$\left(10\right)^{2}$– 107$\left(10\right)^{7}$ S/m. Metal–ceramic irregular metamaterials are proposed
Valentina Torres Nieto, Marcia A. Cooper
wiley   +1 more source

Sulfenamide-enabled ortho thiolation of aryl iodides via palladium/norbornene cooperative catalysis

Nature Communications, 2019
Poly-substituted aromatic sulfur compounds are part of many pharmaceuticals, agrochemicals and organic materials. Here, the authors developed a sulfenamide-enabled ortho-thiolation of aryl iodides via Pd/norbornene cooperative catalysis for the ...
Renhe Li, Yun Zhou, Ki-Young Yoon, Zhe Dong, Guangbin Dong   +4 more
doaj   +1 more source

Order-disorder phase transition driven by interlayer sliding in lead iodides

Nature Communications, 2023
2D layered materials attract interest due to their potential for application in nanoelectronics and optoelectronics. Here authors report an order-disorder-type phase transition driven by temperature in bulk lead iodides, and interlayer sliding is ...
Seyeong Cha, Giyeok Lee, Sol Lee, Sae Hee Ryu, Yeongsup Sohn, Gijeong An, Changmo Kang, Minsu Kim, Kwanpyo Kim, Aloysius Soon, Keun Su Kim   +10 more
doaj   +1 more source

Combinatorial Synthesis of Next Generation Water‐Soluble Quaternized N‐Halamine Oligomers with Long‐Lasting Antiviral Properties

Advanced Functional Materials, EarlyView.
A combinatorial library of dual‐functional antiviral oligomers incorporating N‐halamine and quaternary ammonium functionalities is developed for long‐lasting antiviral activity. The lead materials exhibit rapid and durable antiviral activity against SARS‐CoV‐2 variants and influenza H1N1, with 4 to 5 log reduction in viral copies at 5 mg mL−1 ...
Eid Nassar‐Marjiya, Konda Reddy Kunduru, Krishanu Ghosal, Luna Rizik, Nofar Atari, Mahran Daifa, Neta Kutner, Bassma Khamaisi, Qi Wu, Simran Jindal, Merna Shaheen‐Mualim, Ranabir Majumder, Mahitosh Mandal, Michal Mandelboim, Shady Farah   +14 more
wiley   +1 more source

Conductance of electrolytes in 1-propanol solutions from −40 to 25°C [PDF]

, 1986
Conductance data for solutions of LiCl, NaBr, NaI, KI, KSCN, RbI, Et4NI, Pr4NI, Bu4NI, Bu4NClO4, n-Am4NI, i-Am4NI, n-Hept4NI, Me2Bu2NI, MeBu3NI, EtBu3NI, i-Am3BuNI, and i-Am3BuNBPh4 in 1-propanol at –40, –30, –20, –10, 0, 10, and 25°C are communicated ...
Barthel, Josef, Hilbinger, H., Schmeer, Georg, Wachter, R.   +3 more
core   +1 more source

Biomass Native Structure Into Functional Carbon‐Based Catalysts for Fenton‐Like Reactions

Advanced Functional Materials, EarlyView.
This study indicates that eight biomasses with 2D flaky and 1D acicular structures influence surface O types, morphology, defects, N doping, sp2 C, and Co nanoparticles loading in three series of carbon, N‐doped carbon, and cobalt/graphitic carbon. This work identifies how these structural factors impact catalytic pathways, enhancing selective electron
Wenjie Tian, Jingkai Lin, Zhihao Tian, Selusiwe Ncube, Huayang Zhang, Emiliano Cortés, Hongqi Sun, Shaobin Wang   +7 more
wiley   +1 more source