Results 261 to 270 of about 106,293 (333)

Intravascular Ultrasound Findings Associated With Hydrodynamic Contrast Recanalization (HDR) of Coronary Chronic Total Occlusions

open access: yesCatheterization and Cardiovascular Interventions, EarlyView.
ABSTRACT Background Hydrodynamic contrast recanalization (HDR) is a novel technique to facilitate wire crossing during chronic total occlusion (CTO) percutaneous coronary interventions (PCI). The mechanisms underlying HDR have not been fully described.
Salman A. Arain   +12 more
wiley   +1 more source

Integrating Enzymes with Photoredox Catalysis for Conversion of Nitriles into Fluorinated Products

open access: yesChemCatChem, EarlyView.
Herein, we describe a novel method for producing highly sought‐after fluorinated compounds through the integration of nitrilase enzymes and iridium photoredox catalysis in a convenient one‐pot reaction. Our chemo‐ biocatalytic methodology delivers a range of fluorinated and fluoroalkylated products from simple nitrile precursors, in good yields, at ...
Stuart Angiolini   +6 more
wiley   +1 more source

Sustainable One‐Pot Synthesis of N‐Substituted Pyrroles Using a Multifunctional Cobalt‐Based Catalyst

open access: yesChemCatChem, EarlyView.
The one‐pot synthesis of N‐substituted pyrroles from nitrobenzene and 2,5‐hexanodione is first ever reported with >99% conversion and >99% chemoselectivity, in a green solvent, using a non‐noble metal‐based catalyst and hydrogen as a reductant under mild reaction conditions simultaneously.
Jose Luis del Río‐Rodríguez   +3 more
wiley   +1 more source

Application of Metal‐Organic Framework Composites

open access: yesChemistryEurope, EarlyView.
This review summarizes the applications of MOF composites in adsorption, energy storage, catalysis, biomedicine, and sensing. It also discusses the functionality of MOF composites from a dimensional perspective. Environmental issues have intensified, and demand for energy continues to grow, making it challenging for conventional materials to meet the ...
Yihao Chen   +5 more
wiley   +1 more source

Intracellular Catalytic Photooxygenation of α‐Synuclein Amyloid

open access: yesChemistryEurope, EarlyView.
Amyloid‐selective catalytic photooxygenation reduces amyloid toxicity, aggregation tendencies, and seeding activities. Achieving therapeutic catalysis for intracellular amyloids is challenging due to conflicting oxygenation and reductive cellular environments.
Atsushi Iwai   +11 more
wiley   +1 more source

The Chemistry of Subphthalocyanines: Synthetic Strategies for their Axial, Peripheral, and Remote Postfunctionalization

open access: yesChemistryEurope, EarlyView.
From axial and peripheral reactivity to remote derivatization, the chemical versatility of subphthalocyanines (SubPcs) renders them ideal scaffolds for the design of advanced functional materials. This review assembles the synthetic toolbox, key reaction conditions, and future challenges in SubPc functionalization, guiding the development of next ...
Marta Gómez‐Gómez   +4 more
wiley   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

open access: yesChemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

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