Indole Synthesis via Allenyl Ester; Enantioselective Total Synthesis of Geissoschizoline
An indole synthesis via an allenyl ester intermediate at ambient temperature has been developed. The mild reaction conditions allow the use of a broad range of substrates. Notably, the utility of this approach is demonstrated through the asymmetric total synthesis of geissoschizoline, a Strychnos‐type monoterpenoid indole alkaloid.
Sohsuke Moriue+5 more
wiley +1 more source
High national and sub-national coverage of iodised salt in India: evidence from the first National Iodine and Salt Intake Survey (NISI) 2014-2015. [PDF]
Pandav CS+5 more
europepmc +1 more source
The Azidofunctionalization of Alkenes
The azidofunctionalization of alkenes offers a powerful strategy for synthesizing nitrogen‐containing compounds by installing both an azide and a second functional group in one step. This approach, employing photoredox catalysis, transition metals, and radical methods, is efficient, selective, and versatile, with applications in pharmaceuticals and ...
Pierre Palamini, Jerome Waser
wiley +1 more source
Iodine Status and Iodised Salt Consumption in Portuguese School-Aged Children: The Iogeneration Study. [PDF]
Costa Leite J+28 more
europepmc +1 more source
Iodine deficiency disorders are prevalent in all the States and Union Territories in India. Under the National Iodine Deficiency Disorders control programme, the Government of India has adopted a strategy to iodisation of all edible salt in the country which is a long term and sustainable preventive solution to eliminate iodine deficiency disorders ...
openaire +1 more source
In Situ Generation of Alkyl–λ3–Iodanes as Soft and Highly Reactive Electrophiles
A convenient and practical method for the clean generation of alkyl–λ3–iodanes is reported using tetraalkylsilanes and iodine tris(trifluoroacetate). An in situ‐generated methyl–λ3–iodane works as a soft and highly electrophilic methylation reagent, which enables methylation of tertiary sulfonamides at low temperatures and following transamidation and ...
Rina Katsuta+6 more
wiley +1 more source
Rewriting Alkene Frameworks: A Practical Strategy for Nitrogen Incorporation
Morandi and team developed a metal‐free method to insert nitrogen into unactivated alkenes, forming amidines and nitriles via a transient aza‐allenium intermediate. Using mild, open‐flask conditions, the process delivers high yields and broad functional group tolerance.
Ranjini Laskar, Frank Glorius
wiley +1 more source
Metal halide perovskite quantum dots (PQDs) have been extensively explored due to their unique optical/optoelectronic properties such as tunable wavelength, narrow emission, and high photoluminescence quantum efficiency. This critical review article is an overview of the fabrication methods, degradation mechanisms of PQDs and explores strategies for ...
Sikandar Aftab+6 more
wiley +1 more source
Iodine intake in the Swiss population 100 years after the introduction of iodised salt: a cross-sectional national study in children and pregnant women. [PDF]
Fischer L+4 more
europepmc +1 more source
Use of iodised salt in cheese manufacturing to improve iodine status of population in the UK [PDF]
Iodine is an essential trace mineral. Iodine deficiency during pregnancy can lead to adverse postnatal consequences such as impaired mental development, reduced intelligence scores and impaired motor skills in the offspring of the deficient women (Khazan
Pradhan, Suruchi
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