Asymmetric paired oxidative and reductive catalysis enables enantioselective alkylarylation of olefins with C(sp3)-H bonds. [PDF]
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Comparison of QM Methods for the Evaluation of Halogen-π Interactions for Large-Scale Data Generation. [PDF]
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Palladium-Catalyzed β-C(sp3)-H Bond Arylation of Tertiary Aldehydes Facilitated by 2-Pyridone Ligands. [PDF]
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Reactions of cyclopentadienylcopper(I) tributylphosphine with iodobenzenes
Journal of Organometallic Chemistry, 1973Abstract Cyclopentadienylcopper(I) tributylphosphine reacts with iodobenzenes to give arylcyclopentadienes. If the iodobenzene has strongly electron-attracting substituents, copper—iodine exchange may occur simultaneously. The resulting transient arylcopper compounds have been trapped with acetyl chloride but may otherwise give symmetric biphenyls.
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Chemoenzymatic synthesis of carbasugars from iodobenzene
Organic & Biomolecular Chemistry, 2005The versatile enantiopure cis-dihydrodiol metabolite 1, formed by bacterial metabolism of iodobenzene, has been used for the synthesis of the pyranose carbasugars (pseudosugars) carba-beta-D-altropyranose 2, carba-alpha-L-galactopyranose 3, carba-beta-D-idopyranose 4 and carba-beta-L-glucopyranose 5.
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