Results 111 to 120 of about 1,584,637 (354)

MnI‐Functionalized Covalent Organic Framework as Efficient Electrocatalyst for CO2 Reduction in a Catholyte‐Free Zero‐Gap Electrolyzer

open access: yesAdvanced Functional Materials, EarlyView.
This work demonstrates the successful integration of a phenanthroline‐based 2D COF with MnI catalytic sites into a catholyte‐free membrane‐electrode‐assembly cell for CO2 electroreduction. The crystalline COF actively suppresses Mn⁰–Mn⁰ dimerization, achieving a turnover frequency of 617 h⁻¹ at 2.8 V (full‐cell potential), and enabling stable operation.
Laura Spies   +8 more
wiley   +1 more source

In-situ localised alignment assisted salting-out enhanced ionogels with high strength, toughness and impact resistance

open access: yesNature Communications
Ionic gels have promise in a range of applications but are limited in extreme environments. Here, we report a method for preparation of an ionic gel with improved mechanical properties, through the formation of a micro-orientated structure and increased ...
Zhentao Zhang   +6 more
doaj   +1 more source

Copper Doping Enhances the Activity and Selectivity of Atomically Precise Ag44 Nanoclusters for Photocatalytic CO2 Reduction

open access: yesAdvanced Functional Materials, EarlyView.
By a simple anti‐Galvanic reaction, up to six copper atoms could be preferably doped into the Ag2(SR)5 staple motifs and Ag20 dodecahedral shell of an atomically precise Ag44(SR)30 nanocluster. When anatase TiO2 is used as substrate, the (AgCu)44/TiO2 photocatalyst exhibited much improved activity in photocatalytic CO2 reduction compared to Ag44/TiO2 ...
Ye Liu   +5 more
wiley   +1 more source

Solid-State Esterification via Ionic-to-Covalent Bond Transformation in Ionic Molecular Crystals Consisting of Disubstituted Anthracene Anion-Cation Combinations [PDF]

open access: bronze, 2017
Masato Suzuki   +7 more
openalex   +1 more source

Enhancing CoFe Catalysts with V2CTX MXene‐Derived Materials for Anion Exchange Membrane Electrolyzers

open access: yesAdvanced Functional Materials, EarlyView.
MXene dervied CoFe composites show increased initial Oxygen Evolution Reaction (OER) activity compared to the pure CoFe and MXene in an Anion Exchange Membrane device. Vanadium vacancies in the MXene plays a role in increased OER activity and hinders Fe leaching in the AEM device over using the pure V2C MXene as a support material for the CoFe ...
Can Kaplan   +16 more
wiley   +1 more source

The Role of Ionic Liquids in Direct Synthesis of Formic Acid from CO2 Hydrogenation on Ru Complexes: A Theoretical Study

open access: yesChemistry
Due to high thermodynamic stability, the direct generation of formic acid by CO2 hydrogenation is not easy to achieve experimentally. However, when Nakahara and coworkers studied the equilibrium of formic acid reversibly decomposing into CO2 and H2, they
Pengcheng Gong, Jun Li
doaj   +1 more source

Self‐supportive Three‐Way Photoelectrochemical System Achieving Uranium Recycling, Organic Oxidation, and Electricity Generation in Complex Waters

open access: yesAdvanced Functional Materials, EarlyView.
A self‐sustaining solar photoelectrochemical cell (SS‐PEC) is developed to recover uranium from aqueous UO22+ with concurrent organic oxidation and electricity production. The monolithical photoanode directly captures electrons from organic compounds, leading to the oxidation of organic compounds and the decomposition of uranium‐organic complexes ...
Yumei Wang   +7 more
wiley   +1 more source

uMBD: A Materials-Ready Dispersion Correction that Uniformly Treats Metallic, Ionic, Covalent, and van der Waals Bonding

open access: gold, 2019
Minho Kim   +5 more
openalex   +1 more source

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