Synthesis and spectroscopic studies of new leucine acid derivative with their metal complexes. [PDF]
A new ligand N-[(acetyl amino)-thioxo methyl]leucine(ATL) are synthesized by reaction of acetyl-isothio cyanate with leucine acid. The ligand is characterized by elemental analysis, FT-IR and NMR spectra, some transition metal complex of this ligand were
Muhammed Ahmed.Awaad +2 more
doaj +1 more source
Five new derivatives of N-(4-oxo-2-thioxothiazolidin-3-yl)-2-((3-aryl-4-oxo-3,4-dihydroquinazolin-2-yl)thio) acetamides have been synthesized successfully through a four-step process from anthranilic acid and aryl isothiocyanates as starting materials ...
Tien Cong Nguyen +3 more
doaj +1 more source
A Homologous Series of Cobalt, Rhodium, and Iridium Metalloradicals [PDF]
We herein present a series of d7 trimethylphosphine complexes of group 9 metals that are chelated by the tripodal tetradentate tris(phosphino)silyl ligand [SiP^(iPr)_3]H ([SiP^(iPr)_3] = (2_(-i)Pr_2PC_6H_4)_3Si^–).
Peters, Jonas C., Takaoka, Ayumi
core +1 more source
Organoaluminium complexes derived from Anilines or Schiff bases for ring opening polymerization of epsilon-caprolactone, delta-valerolactone and rac-lactide [PDF]
Reaction of R¹R²CHN=CH(3,5-tBu₂C₆H₂-OH-2) (R¹ = R² = Me L¹H; R¹ = Me, R² = Ph L²H; R¹ = R2 = Ph L³H) with one equivalent of R³3Al (R³ = Me, Et) afforded [(L¹-³)AlR³₂] (L¹, R³ = Me 1, R³ = Et 2; L², R³ = Me 3, R³ = Et 4; L³ R³ = Me 5, R³ = Et 6); complex ...
Al-Khafaj, Yahya +13 more
core +3 more sources
Deciphering Small Molecule Diffusion Parameters Across Light Responsive Polymersome Membranes
Light‐responsive polymersomes bearing donor–acceptor Stenhouse adducts (DASAs) enable programmable control over small‐molecule transport across synthetic membranes. By systematically varying DASA density, an optimal functionalization regime is identified that maximizes light‐gated permeability.
Farzina Matubbar +7 more
wiley +1 more source
Boric Acid Catalyzed Convenient Synthesis of Benzimidazoles in Aqueous Media
Synthesis of benzimidazoles has been developed by the o-phenylenediamine with aldehydes using boric acid an efficient catalyst under mild reaction conditions in aqueous media. The product is applicable to aryl and heteroaryl aldehydes.
Mohammad Reza Poor Heravi, Marjan Ashori
doaj +1 more source
Synthesis and Characterization of Some New 4-Hydroxy-coumarin Derivatives
Some novel coumarins were synthesized starting from 4-hydroxycoumarin and methyl bromoacetate. The structures of the newly obtained compounds were confirmed by elemental analysis, mass, IR and NMR spectra.
Yasameen K. Al-Majedy +3 more
doaj +1 more source
A prompt and modular copper(I)-catalyzed azide–alkyne cycloaddition ʼclickʼ approach has been exploited for the synthesis of galactose- and mannose-coated calixarene-cored G1 generation glycodendrimers.
Sunil Kumar +6 more
doaj +1 more source
Jahn-Teller orbital glass state in the expanded fcc Cs3C60 fulleride [PDF]
The most expanded fcc-structured alkali fulleride, Cs3C60, is a Mott insulator at ambient pressure because of the weak overlap between the frontier t1u molecular orbitals of the C603− anions.
Arcon, D. +9 more
core +1 more source
Sustainable Catalyst‐Free PLG Networks: Recyclability, Biodegradability, and Functional Performance
A catalyst‐additive free covalent adaptable network is developed from star‐shaped poly(lactide‐co‐glycolide) cross‐linked with pyromellitic dianhydride, enabling internal carboxylic acid‐driven transesterification. The resulting biodegradable network exhibits mechanical robustness (Young's modulus ≈1.6 GPa), complete recyclability, rapid biodegradation
Lars Schwarzer +2 more
wiley +1 more source

