Results 221 to 230 of about 111,450 (307)

Ir Complexes With Mixed‐Valent Bidentate Ligands: From Complex Synthesis to Catalytic Application

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT The bidentate ligands Ph2P(E)NHPPh2 (E = S, Se) feature phosphorous atoms in two different oxidation states and provide the potential to tune chemical reactivity through the choice of donor E. The mononuclear complexes [Ir(COD){κ2‐P,E‐Ph2P(E)NPPh2}] (E = S 1a, Se 1b) were prepared from the dimer [IrClCOD]2 (COD = 1,5‐cyclooctadiene) and the ...
C. Gabriela Morales Salas   +4 more
wiley   +1 more source

Light, Redox, and Ligand Noninnocence Cooperate in Naphthalene Diimide‐Functionalized N‐Heterocyclic Carbene Iridium Complexes

open access: yesChemistry – A European Journal, EarlyView.
Naphthalene diimide–N‐heterocyclic carbene iridium complexes display uncommon multistimuli‐responsive behavior combining strong Cl(lp)···π interactions, ligand non‐innocence, visible‐light photoreduction, and conPET photocatalysis. The study also provides new insight into the interaction of NDI platforms with fluoride/basic anions, revealing unexpected
Maite Silva‐Muñoz   +2 more
wiley   +1 more source

Incidence of Invasive Pneumococcal Disease in US Children by Risk Group, 1998-2023. [PDF]

open access: yesJ Pediatric Infect Dis Soc
Mohanty S   +13 more
europepmc   +1 more source

C‐Terminal Functionalization Methods of Amino Acids, Peptides, and Proteins

open access: yesChemistry – A European Journal, EarlyView.
C‐terminal functionalization offers powerful routes to peptide and protein diversification, yet epimerization, hydrolysis, and selectivity remain key challenges. This Review surveys enzymatic, decarboxylative, and condensation strategies, highlighting advances toward chemo‐ and regioselective, protecting‐group‐free, atom‐efficient methods applicable to
Jay Hanssens   +3 more
wiley   +1 more source

Trends and Future Directions in Organic Chemistry for Drug Discovery

open access: yesChemistry – A European Journal, EarlyView.
Organic synthesis is being reshaped by the convergence of catalytic innovation, automation, artificial intelligence, and emerging therapeutic modalities. Late‐stage functionalization, photoredox and electrochemical methods, biocatalysis, flow chemistry, DELs, and proximity‐based drugs are examined as components of closed‐loop discovery.
Paweł Kozyra, Maciej Masłyk
wiley   +1 more source

Targeting the IRE1α/XBP1 pathway in type 2 diabetes mellitus: from ER stress signaling to therapeutic opportunity. [PDF]

open access: yesMol Biol Rep
Obafemi OT   +6 more
europepmc   +1 more source

A Naphthalenediimide–Imidazolium Macrocycle for Orthogonal Molecular Recognition

open access: yesChemistry – A European Journal, EarlyView.
One host, two recognition modes: a naphthalenediimide–imidazolium macrocycle switches between π‐driven encapsulation and hydrogen‐bonding to bind structurally diverse molecular and metal‐complex guests. ABSTRACT A naphthalenediimide‐imidazolium macrocycle is shown to function as a dual‐site supramolecular host for orthogonal molecular recognition.
Joel Martínez‐Visiedo   +2 more
wiley   +1 more source

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