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Cryogenic cationic polymerization of isobutylene
2023A large number of unsaturated hydrocarbon compounds undergo cationic polymerization upon the addition of a Lewis acid catalyst. Isobutylene (IB) is one of the most active and widely used monomers for polymerization. Previous studies suggest that isobutylene polymerizes by cationic polymerization using Lewis acids such as AlCl3, TiCl4, BF3, and SnCl4 ...
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Enterprise to build isobutylene plant
C&EN Global Enterprise, 2017Enterprise Products Partners plans to build an isobutane dehydrogenation plant at its facility in Mont Belvieu, Texas. The plant will open by 2019 and have 425,000 metric tons of annual isobutylene capacity. Increased use of shale-derived ethane as a feedstock for ethylene crackers has diminished the availability of C4 chemicals, Enterprise says.
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Allyl- and Hydroxytelechelic Poly(isobutylenes)
2008Telechelic polyisobutylenes with low polydispersities and defined chain lengths can be obtained by quasiliving cationic polymerization of isobutylene in high yields up to molecular weights of 105 g mol−1. Ally- and hydroxyl-endgroups can be introduced quantitatively.
W. H. Binder, R. Zirbs
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Analyse der Sequenzverteilung in Isobutylen/Styrol- und Isobutylen/Isopren-Copolymeren
Colloid and Polymer Science, 1978J. P. Kennedy, T. Chou
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Journal of the American Chemical Society, 1950
Francis Owen Rice, Leo A. Wall
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Francis Owen Rice, Leo A. Wall
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