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Critical study of the isoconversional methods of kinetic analysis [PDF]
Journal of Thermal Analysis and Calorimetry, 2008 A critical study of the use of isoconversional methods for the kinetic analysis of non-isothermal data corresponding to processes with either a real or an apparent variation of the activation energy, E, with the reacted fraction, α, has been carried out ...
Criado Luque, José Manuel +2 more
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FoodsIn this study, the decomposition processes of tabletop sweeteners based on steviol glycosides were investigated to determine the kinetic parameters of activation energy (Ea) and the logarithm of the pre-exponential factor (ln A) based on the converted fraction (α).
Naienne da Silva Santana +3 more
doaj +5 more sources
Kinetic Prediction of Fast Curing Polyurethane Resins by Model-Free Isoconversional Methods [PDF]
Polymers, 2018 In this work, the characterisation of reaction kinetics of a methylene diphenyl diisocyanate (MDI)-based fast curing polyurethane resin (PUR) and the mathematical description of its curing process are presented. For the modelling of the reaction process isoconversional methods, which are also called model-free approaches, are used instead of model ...
Michael Stanko, Markus Stommel
exaly +6 more sources
Advanced Isoconversional Kinetic Analysis for the Elucidation of Complex Reaction Mechanisms: A New Method for the Identification of Rate-Limiting Steps [PDF]
Molecules, 2019 Two complex cure mechanisms were simulated. Isoconversional kinetic analysis was applied to the resulting data. The study highlighted correlations between the reaction rate, activation energy dependency, rate constants for the chemically controlled part ...
Nicolas Sbirrazzuoli
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The catalytic thermo-oxidative decomposition of glimepiride using the isoconversional method [PDF]
Journal of Thermal Analysis and Calorimetry, 2022 AbstractApplying the isoconversional method to data obtained from thermogravimetric analysis (TGA) can provide vital kinetic information. In this work, the thermal decomposition and oxidation of the antidiabetic drug glimepiride is analyzed in the presence of N2and O2. The study was done with and without metal oxide catalysts to explore their potential
Najamus Sahar Riyaz, Ismail Badran
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Kinetic compensation effect of isoconversional methods [PDF]
Reaction Kinetics, Mechanisms and Catalysis, 2020 AbstractFor experimental data obtained under different reaction/process conditions over time or temperature, the kinetic compensation effect (KCE) can be expected. Under dynamic (nonisothermal) conditions, at least two analytical pathways forming the KCE were found.
A. Mianowski +2 more
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Thermogravimetric analysis of high-density cork granules using isoconversional methods
Energy Reports, 2022 In the present work thermogravimetric techniques were used to study the thermal degradation of high-density cork granules. Pyrolysis experiments were carried out for four heating ramps (10, 15, 20 and 25 °C.min−1), using nitrogen as the carrier gas. From
Albina Ribeiro +3 more
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Vetor, 2022 Cellulose acetate membranes are widely used in industry, emphasizing water purification processes, such as desalination. With some limiting mechanical properties, the synthesis of hybrid membranes appears as an alternative for developing high ...
Gesiane Mendonça Ferreira +4 more
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Materials Science for Energy Technologies, 2023 The growing global demand for fish has led to an increase in fish waste (FW) production, necessitating efficient waste management strategies. Pyrolysis is a promising way to convert fish waste into high-value products.
Nurul Iffah Farhah Mohd Yusof +3 more
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Kinetic Studies on the Steam Gasification of Chars Derived from Coals by Different Isoconversional Methods [PDF]
Atmosphere, 2022 Previous studies have successfully assessed the extent to which a kinetic model accurately represents a specific reaction mechanism by comparing the kinetic parameters derived from the kinetic model to those obtained using isoconversional methods ...
Mei An, Qingjie Guo
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